journal article·2026-01-01Open access

Freestanding SrNbO3 membranes as flexible transparent conductors

Eun Kyo Ko, Bai Yang Wang, Ji Hye Lee, Jiayue Wang, Kevin J. Crust, Harold Y. Hwang

APL Materials· Volume 14· Issue 1

Abstract

Synthesizing flexible transparent conducting materials is important for applications in flexible optoelectronics. Metallic oxide membranes offer great promise due to their large elasticity and high transparency. Among them, SrNbO3, a correlated metal, stands out as a promise transparent conducting oxide. However, synthesizing freestanding SrNbO3 membranes poses a challenge because it easily undergoes oxidation, resulting in degraded conductivity. To address this, we utilize epitaxial BaTiO3 capping layers, which effectively prevents SrNbO3 oxidation. We successfully fabricate millimeter-sized transparent conducting BaTiO3/SrNbO3/BaTiO3 membranes using water-soluble sacrificial layers. The obtained SrNbO3 (10 nm thick) membrane exhibits a room temperature sheet resistance (RS) of 174 Ω/sq and a transmittance (T) of 92% at a wavelength of 550 nm. The figure of merit (T10/RS) of this transparent conductor reaches 2.2 × 10−3 Ω−1 in the visible regime, comparable to SrNbO3 films on rigid substrates. These results open possibilities for applications as flexible transparent conductors.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Electronic and Structural Properties of Oxides · Nanomaterials and Printing Technologies · Ferroelectric and Piezoelectric Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory 1 , Menlo Park, California 94025,

Department of Applied Physics, Stanford University 2 , Stanford, California 94305,

Department of Physics, Stanford University 3 , Stanford, California 94305,

Advanced Institute of Convergence Technology, Seoul National University 4 , Suwon 16229,

Funding

U.S. Department of Energy · National Science Foundation

References (38)

Show source-provided references
1. Fully integrated wearable sensor arrays for multiplexed in situ perspiration analysis10.1038/nature16521 ↗
2. High-speed and large-scale intrinsically stretchable integrated circuits10.1038/s41586-024-07096-7 ↗
3. Epidermal electronics10.1126/science.1206157 ↗
4. Multifunctional wearable devices for diagnosis and therapy of movement disorders10.1038/nnano.2014.38 ↗
5. Emerging self-emissive technologies for flexible displays10.1002/adma.201902391 ↗
6. Flexible electronics: Stretchable electrodes and their future10.1002/adfm.201805924 ↗
7. Printable transparent conductive films for flexible electronics10.1002/adma.201704738 ↗
8. Transparent conducting oxides10.1557/mrs2000.256 ↗
9. Past achievements and future challenges in the development of optically transparent electrodes10.1038/nphoton.2012.282 ↗
10. Freestanding perovskite oxide films: Synthesis, challenges, and properties10.1002/andp.202200084 ↗
11. Extreme tensile strain states in La0.7Ca0.3MnO3 membranes10.1126/science.aax9753 ↗
12. Super-flexibility in freestanding single-crystal SrRuO3 conductive oxide membranes10.1021/acsaelm.2c00422 ↗
13. Correlated metals as transparent conductors10.1038/nmat4493 ↗
14. SrNbO3 as a transparent conductor in the visible and ultraviolet spectra10.1038/s42005-020-0372-9 ↗
15. Optical plasmon excitation in transparent conducting SrNbO3 and SrVO3 thin films10.1002/adom.202100520 ↗
16. Transparent conducting oxides SrNbO3 thin film with record high figure of merit10.1016/j.jeurceramsoc.2024.04.050 ↗
17. Synthesis of freestanding single-crystal perovskite films and heterostructures by etching of sacrificial water-soluble layers10.1038/nmat4749 ↗
18. Large-area crystalline BaSnO3 membranes with high electron mobilities10.1021/acsaelm.9b00215 ↗
19. Stabilization of Sr3Al2O6 growth templates for Ex situ synthesis of freestanding crystalline oxide membranes10.1021/acs.nanolett.1c01194 ↗
20. Freestanding crystalline YBa2Cu3O7−x heterostructure membranes10.1103/physrevmaterials.3.060801 ↗
21. Strain-induced room-temperature ferroelectricity in SrTiO3 membranes10.1038/s41467-020-16912-3 ↗
22. Periodic wrinkle-patterned single-crystalline ferroelectric oxide membranes with enhanced piezoelectricity10.1002/adma.202004477 ↗
23. Highly flexible freestanding BaTiO3-CoFe2O4 heteroepitaxial nanostructure self-assembled with room-temperature multiferroicity10.1002/smll.202104213 ↗
24. Phase transition enhanced superior elasticity in freestanding single-crystalline multiferroic BiFeO3 membranes10.1126/sciadv.aba5847 ↗
25. Freestanding oxide membranes for epitaxial ferroelectric heterojunctions10.1021/acsnano.3c01974 ↗
26. Super-tetragonal Sr4Al2O7 as a sacrificial layer for high-integrity freestanding oxide membranes10.1126/science.adi6620 ↗
27. Synthesis of superconducting freestanding infinite-layer nickelate heterostructures on the millimetre scale10.1038/s44160-024-00714-2 ↗
28. Ultrathin epitaxial barrier layer to avoid thermally induced phase transformation in oxide heterostructures10.1021/acsami.6b14106 ↗
29. Surface stability of SrNbO3+δ grown by hybrid molecular beam epitaxy10.1063/5.0097699 ↗
30. Oxygen-driven metal–insulator transition in SrNbO3 thin films probed by infrared spectroscopy10.1002/aelm.202101338 ↗
31. Modulation of the optical and transport properties of epitaxial SrNbO3 thin films by defect engineering10.1063/5.0179267 ↗
32. Tunable and low-loss correlated plasmons in Mott-like insulating oxides10.1038/ncomms15271 ↗
33. Intrinsic high electrical conductivity of stoichiometric SrNbO3 epitaxial thin films10.1103/physrevb.92.205102 ↗
34. Sputtered SrxNbO3 as a UV-transparent conducting film10.1021/acsami.0c04854 ↗
35. Enhanced oxygen evolution reaction by stacking single-crystalline freestanding SrRuO310.1016/j.apcatb.2022.121781 ↗
36. Oxygen vacancy dipoles in strained epitaxial BaTiO3 films10.1103/PhysRevResearch.2.023056 ↗
37. Single-crystalline-level properties of ultrathin SrRuO3 flexible membranes with wide and clean surface10.1038/s41528-022-00155-x ↗
38. New figure of merit for transparent conductors10.1063/1.323240 ↗