journal article·2016-04-01Open access

Intrinsic and extrinsic effects on the ferroelectric switching of thin poly(vinylidene fluoride/trifluoroethylene) copolymer films

Manfang Mai, Shanming Ke, Peng Lin, Xierong Zeng

APL Materials· Volume 4· Issue 4

Abstract

In this paper, intrinsic and extrinsic factors dependent switching process in P(VDF-TrFE) thin films is investigated through time domain polarization measurements. The thinning-induced increase of switching time is observed for samples below 80 nm due to the surface oxide layer. For thinner samples the switchable polarization decreases with decreasing temperature since domain pinning prevails. Switching is faster using metal electrode with higher work function, which can be attributed to the lower depolarization field. Furthermore, the switching time increases with increasing the waiting time and increasing the pulse width of the prepolarization pulse caused by imprint effect.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Dielectric materials and actuators · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Shenzhen University 1 Shenzhen Key Laboratory of Special Functional Materials, College of Materials Science and Engineering, , Shenzhen 518060, China

Shenzhen University 2 Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, , Shenzhen 518060, China

Funding

Science and Technology Research Items of Shenzhen · National Natural Science Foundation of China · China Postdoctoral Science Foundation

References (35)

Show source-provided references
1. J. Appl. Phys. · 2006 · 100 · 02411010.1063/1.2218463 ↗
2. Appl. Phys. Lett. · 2007 · 90 · 16290210.1063/1.2723678 ↗
3. Nat. Mater. · 2005 · 4 · 24310.1038/nmat1329 ↗
4. J. Appl. Phys. · 2010 · 107 · 12411910.1063/1.3437638 ↗
5. 2010 · 395
6. Nat. Mater. · 2011 · 10 · 29610.1038/nmat2951 ↗
7. Nano Lett. · 2011 · 11 · 386210.1021/nl201965r ↗
8. Phase Transitions · 1989 · 18 · 14310.1080/01411598908206863 ↗
9. Polymer · 2010 · 51 · 357510.1016/j.polymer.2010.05.021 ↗
10. Ferroelectrics · 2010 · 409 · 4110.1080/00150193.2010.485893 ↗
11. Polymer · 2007 · 48 · 322610.1016/j.polymer.2007.04.015 ↗
12. 1996
13. J. Appl. Phys. · 2010 · 108 · 09410210.1063/1.3500428 ↗
14. J. Appl. Phys. · 2011 · 110 · 11410610.1063/1.3660680 ↗
15. Phys. Rev. Lett. · 2000 · 84 · 17510.1103/PhysRevLett.84.175 ↗
16. J. Mater. Chem. C · 2013 · 1 · 769510.1039/c3tc31774a ↗
17. J. Appl. Phys. · 2011 · 110 · 06410110.1063/1.3636397 ↗
18. 2007 · 729
19. J. Appl. Phys. · 2013 · 114 · 05410410.1063/1.4817508 ↗
20. Phys. Status Solidi B · 2006 · 243 · 291310.1002/pssb.200541428 ↗
21. J. Appl. Phys. · 1956 · 27 · 93810.1063/1.1722518 ↗
22. J. Phys. Soc. Jpn. · 1992 · 61 · 465010.1143/JPSJ.61.4650 ↗
23. J. Phys. D: Appl. Phys. · 2005 · 38 · 186010.1088/0022-3727/38/12/002 ↗
24. J. Phys. Soc. Jpn. · 1994 · 63 · 160110.1143/JPSJ.63.1601 ↗
25. Phys. Rev. B · 2002 · 66 · 21410910.1103/PhysRevB.66.214109 ↗
26. J. Electrost. · 2009 · 67 · 20310.1016/j.elstat.2009.01.042 ↗
27. Phys. Rev. · 1959 · 116 · 6110.1103/PhysRev.116.61 ↗
28. Phys. Rev. B · 1990 · 42 · 857710.1103/PhysRevB.42.8577 ↗
29. Phys. Status Solidi B · 2008 · 245 · 21310.1002/pssb.200743272 ↗
30. Ferroelectrics · 2008 · 370 · 20710.1080/00150190802381696 ↗
31. MRS Proc. · 2002 · 734 · B9.2010.1557/PROC-734-B9.20 ↗
32. IEEE Trans. Electron Devices · 2001 · 48 · 226610.1109/16.954465 ↗
33. Braz. J. Phys. · 1999 · 29 · 29510.1590/S0103-97331999000200011 ↗
34. J. Appl. Phys. · 1988 · 64 · 202610.1063/1.341733 ↗
35. IEEE Trans. Dielectr. Electr. Insul. · 2010 · 17 · 106610.1109/TDEI.2010.5539676 ↗