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journal article·2015-04-01Open access

Soft chemical control of the crystal and magnetic structure of a layered mixed valent manganite oxide sulfide

Jack N. Blandy, Artem M. Abakumov, Kirsten E. Christensen, Joke Hadermann, Paul Adamson, Simon J. Cassidy, Silvia Ramos, David G. Free, Harry Cohen, Daniel N. Woodruff, Amber L. Thompson, Simon J. Clarke

APL Materials· Volume 3· Issue 4
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Source abstract

Abstract

Oxidative deintercalation of copper ions from the sulfide layers of the layered mixed-valent manganite oxide sulfide Sr2MnO2Cu1.5S2 results in control of the copper-vacancy modulated superstructure and the ordered arrangement of magnetic moments carried by the manganese ions. This soft chemistry enables control of the structures and properties of these complex materials which complement mixed-valent perovskite and perovskite-related transition metal oxides.
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Research context

Electronic materials

OpenAlex topics: Magnetic and transport properties of perovskites and related materials · Advanced Condensed Matter Physics · Iron-based superconductors research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

University of Oxford 1 Inorganic Chemistry Laboratory, Department of Chemistry, , South Parks Road, Oxford OX1 3QR, United Kingdom

Diamond Light Source Ltd. 2 , Harwell Science and Innovation Campus, Didcot OX11 0DE, United Kingdom

University of Antwerp 3 Electron Microscopy for Materials Science (EMAT), , Groenenborgerlaan 171, B-2020 Antwerp, Belgium

University of Kent 4 School of Physical Sciences, Ingram Building, , Canterbury, Kent CT2 7NH, United Kingdom

Funding

Engineering and Physical Sciences Research Council

References (12)

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