Cystamine-configured lead halide based 2D hybrid molecular crystals: Synthesis and photoluminescence systematics
Source abstract
Abstract
We have synthesized and studied a specific family of disulfide bridge based 2D organic inorganic hybrid perovskites using the cation, cystamine [2,2′-dithiobis(ethylammonium), abbreviated as SS] in the three lead halide (X = I, Br, and Cl) based systems, and explored their unique photo-physical properties. Green, blue, and white emissions are noted in I, Br, and Cl based systems, respectively. The experimental observations are compared with the results of first principles DFT calculations. The role of the halide ion (X) in the [Pb-X4] cages on the luminescence of the disulfide bridge based hybrid system is elucidated, and the corresponding systematics are analyzed.
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Research context
OpenAlex topics: Perovskite Materials and Applications · Organic and Molecular Conductors Research · 2D Materials and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Physics and Center for Energy Science, Indian Institute of Science Education and Research (IISER) 1 , Pune 411008, India
Department of Physics, Savitribai Phule Pune University 2 , Pune 411007, India
LITEN Group, CEA Grenoble 3 , 17 Avenue des Martyrs, 38054 Grenoble Cedex 9, France
Materials Theory Division, Department of Physics and Astronomy, Uppsala University 4 , Box-516, Uppsala SE-75120, Sweden
References (60)
Show source-provided references
1. J. Chem. Soc., Dalton Trans. · 2001 · 0 · 110.1039/b007070j ↗
2. J. Am. Chem. Soc. · 2009 · 131 · 605010.1021/ja809598r ↗
3. Nanoscale · 2011 · 3 · 408810.1039/c1nr10867k ↗
4. Science · 2012 · 338 · 64310.1126/science.1228604 ↗
5. Sci. Rep. · 2012 · 2 · 59110.1038/srep00591 ↗
6. Adv. Mater. · 2015 · 27 · 510210.1002/adma.201502294 ↗
7. NREL · Sol. Cell Effic. Chart · 2017 · 1 · 1
8. Chem. Rev. · 2016 · 116 · 455810.1021/acs.chemrev.5b00715 ↗
9. Nature · 2016 · 536 · 31210.1038/nature18306 ↗
10. ACS Energy Lett. · 2018 · 3 · 5410.1021/acsenergylett.7b00926 ↗
11. J. Phys. Chem. Lett. · 2016 · 7 · 123110.1021/acs.jpclett.6b00248 ↗
12. Inorg. Chem. · 2017 · 56 · 929110.1021/acs.inorgchem.7b01094 ↗
13. ChemSusChem · 2017 · 10 · 372210.1002/cssc.201701093 ↗
14. ACS Energy Lett. · 2017 · 3 · 5410.1021/acsenergylett.7b00926 ↗
15. Adv. Mater. · 2008 · 20 · 101310.1002/adma.200701753 ↗
16. Adv. Mater. · 2018 · 30 · 170421710.1002/adma.201704217 ↗
17. ACS Nano · 2017 · 11 · 1224710.1021/acsnano.7b05726 ↗
18. Adv. Mater. · 2016 · 28 · 680410.1002/adma.201600669 ↗
19. Adv. Energy Mater. · 2017 · 7 · 170026710.1002/aenm.201700267 ↗
20. CrystEngComm · 2010 · 12 · 264610.1039/c001929a ↗
21. Adv. Mater. · 2017 · 29 · 160418610.1002/adma.201604186 ↗
22. Chem. Sci. · 2017 · 8 · 196010.1039/c6sc02848a ↗
23. J. Phys. Chem. Lett. · 2014 · 5 · 142110.1021/jz5005285 ↗
24. Nat. Commun. · 2018 · 9 · 210.1038/s41467-018-03702-1 ↗
25. J. Lumin. · 2017 · 188 · 56710.1016/j.jlumin.2017.04.067 ↗
26. Mater. Today · 2017 · 20 · 41310.1016/j.mattod.2017.03.021 ↗
27. J. Am. Chem. Soc. · 2014 · 136 · 171810.1021/ja411045r ↗
28. J. Am. Chem. Soc. · 2014 · 136 · 1315410.1021/ja507086b ↗
29. Chem. Sci. · 2017 · 8 · 449710.1039/c7sc01590a ↗
30. J. Am. Chem. Soc. · 2017 · 139 · 521010.1021/jacs.7b01312 ↗
31. ACS Energy Lett. · 2017 · 2 · 41710.1021/acsenergylett.6b00659 ↗
32. J. Mater. Chem. C · 2017 · 5 · 277110.1039/c7tc00366h ↗
33. J. Am. Chem. Soc. · 2017 · 139 · 3910.1021/jacs.6b10390 ↗
34. J. Phys. Chem. Lett. · 2016 · 7 · 225810.1021/acs.jpclett.6b00793 ↗
35. Chem. Mater. · 2017 · 29 · 394710.1021/acs.chemmater.7b00073 ↗
36. J. Phys. Chem. C · 2015 · 119 · 2363810.1021/acs.jpcc.5b06211 ↗
37. Acc. Chem. Res. · 2018 · 51 · 61910.1021/acs.accounts.7b00433 ↗
38. J. Alloys Compd. · 2017 · 699 · 112210.1016/j.jallcom.2017.01.032 ↗
39. J. Am. Chem. Soc. · 2017 · 139 · 1863210.1021/jacs.7b10223 ↗
40. ChemSusChem · 2017 · 10 · 376510.1002/cssc.201701227 ↗
41. Opt. Mater. · 2017 · 66 · 30210.1016/j.optmat.2017.02.020 ↗
42. ACS Photonics · 2018 · 5 · 159910.1021/acsphotonics.8b00052 ↗
43. Adv. Opt. Mater. · 201810.1002/adom.201800751 ↗
44. Eur. J. Inorg. Chem. · 2008 · 165410.1002/ejic.200701253 ↗
45. CrystEngComm · 2007 · 9 · 29810.1039/b617178h ↗
46. J. Chem. · 2013 · 66 · 263
47. CrystEngComm · 2010 · 12 · 129010.1039/b917824d ↗
48. Polyhedron · 1989 · 8 · 283710.1016/s0277-5387(00)80545-8 ↗
49. Angew. Chem. · 2006 · 45 · 210010.1002/anie.200503423 ↗
50. Eur. J. Inorg. Chem. · 2008 · 359210.1002/ejic.200800525 ↗
51. Solid State Sci. · 2008 · 10 · 126910.1016/j.solidstatesciences.2007.12.034 ↗
52. Eur. J. Inorg. Chem. · 2014 · 36410.1002/ejic.201301017 ↗
53. Powder Diffr. · 2015 · 30 · 16310.1017/s0885715614001390 ↗
54. Dalton Trans. · 2007 · 2 · 96510.1039/b617225c ↗
55. J. Phys. Chem. Lett. · 2015 · 6 · 291310.1021/acs.jpclett.5b01309 ↗
56. J. Res. Natl. Bur. Stand., Sect. A · 1976 · 80 · 56710.6028/jres.080a.056 ↗
57. Chem. Mater. · 2017 · 29 · 708310.1021/acs.chemmater.7b02594 ↗
58. Nat. Commun. · 2017 · 8 · 1405110.1038/ncomms14051 ↗
59. Phys. Rev. B · 1993 · 47 · 55810.1103/physrevb.47.558 ↗
60. Phys. Rev. B · 1996 · 54 · 1116910.1103/physrevb.54.11169 ↗