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journal article·2018-11-01Open access

Structure-controlled optical thermoresponse in Ruddlesden-Popper layered perovskites

D. Cortecchia, S. Neutzner, J. Yin, T. Salim, A. R. Srimath Kandada, A. Bruno, Y. M. Lam, J. Martí-Rujas, A. Petrozza, C. Soci

APL Materials· Volume 6· Issue 11
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Source abstract

Abstract

Ruddlesden-Popper perovskites are highly attractive for light-emitting and photonic applications. In these exceptionally deformable frameworks, structural properties strongly impact on the energetic landscape of the material; thus, it is crucial to establish a correlation between the structure and optoelectronic characteristics. Here, we study the structural transformations induced by phase transitions in the butylammonium-based series (BA)2(MA)n−1[PbnI3n+1] (n = 1 and n = 2). We show how thermally driven lattice contraction and changes in crystal packing affect their characteristic absorption and photoluminescence. These findings provide new insights for functional perovskites’ rational design, highlighting the possibility to tune the structural properties through external stimuli to control their functionalities on-demand.
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Research context

Electronic materials

OpenAlex topics: Perovskite Materials and Applications · 2D Materials and Applications · Solid-state spectroscopy and crystallography

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Interdisciplinary Graduate School, Nanyang Technological University 1 , Singapore 639798

Energy Research Institute @NTU (ERI@N), Nanyang Technological University 2 , 50 Nanyang Drive, Singapore 6375532

Istituto Italiano di Tecnologia, Centre for Nano Science and Technology (CNST@PoliMi) 3 , Milan 20133,

Division of Physical Science and Engineering, King Abdullah University of Science and Technology (KAUST) 4 , Thuwal 23955-6900,

School of Material Science and Engineering, Nanyang Technological University 5 , 50 Nanyang Avenue, Singapore 639798,

Dipartimento di Chimica Materiali e Ingegneria Chimica. “Giulio Natta,” Politecnico di Milano 6 , Via Luigi Mancinelli 7, 20131 Milan,

Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University 7 , Singapore 637371,

Funding

Cariplo Foundation - IPER-LUCE · Ministry of Education Singapore · National Research Fundation Singapore

References (57)

Show source-provided references
1. Adv. Energy Mater. · 2017 · 7 · 170026410.1002/aenm.201700264 ↗
2. Mater. Today · 2017 · 20 · 41310.1016/j.mattod.2017.03.021 ↗
3. Science · 2015 · 350 · 122210.1126/science.aad1818 ↗
4. Nat. Commun. · 2015 · 6 · 738310.1038/ncomms8383 ↗
5. Sci. Rep. · 2016 · 6 · 3725410.1038/srep37254 ↗
6. Nat. Photonics · 2016 · 10 · 33310.1038/nphoton.2016.41 ↗
7. Nat. Photonics · 2016 · 10 · 58510.1038/nphoton.2016.139 ↗
8. Adv. Mater. · 2017 · 29 · 160426810.1002/adma.201604268 ↗
9. Nat. Photonics · 2017 · 11 · 78410.1038/s41566-017-0047-6 ↗
10. Nat. Photonics · 2016 · 10 · 29510.1038/nphoton.2016.62 ↗
11. Nat. Rev. Mater. · 2017 · 2 · 1609910.1038/natrevmats.2016.99 ↗
12. Mater. Chem. Front. · 2017 · 1 · 180410.1039/c7qm00157f ↗
13. 2011 · 117
14. Nat. Mater. · 2005 · 4 · 68510.1038/nmat1454 ↗
15. Nat. Photonics · 2017 · 11 · 46510.1038/nphoton.2017.126 ↗
16. IEEE Photonics J. · 2015 · 7 · 110.1109/jphot.2015.2413594 ↗
17. Chem. Mater. · 2016 · 28 · 425910.1021/acs.chemmater.6b00968 ↗
18. Inorg. Chem. · 2005 · 44 · 469910.1021/ic050244q ↗
19. Inorg. Chem. · 2017 · 56 · 840810.1021/acs.inorgchem.7b01096 ↗
20. J. Am. Chem. Soc. · 2017 · 139 · 3910.1021/jacs.6b10390 ↗
21. Inorg. Chem. · 2017 · 56 · 929110.1021/acs.inorgchem.7b01094 ↗
22. Phys. Rev. Mater. · 2018 · 2 · 02540110.1103/physrevmaterials.2.025401 ↗
23. ChemPlusChem · 2017 · 82 · 68110.1002/cplu.201600477 ↗
24. Sci. Rep. · 2016 · 6 · 3568510.1038/srep35685 ↗
25. ACS Energy Lett. · 2016 · 1 · 88010.1021/acsenergylett.6b00381 ↗
26. Chem. Rev. · 2016 · 116 · 455810.1021/acs.chemrev.5b00715 ↗
27. Chem. Sci. · 2017 · 8 · 449710.1039/c7sc01590a ↗
28. J. Am. Chem. Soc. · 2017 · 139 · 1195610.1021/jacs.7b06143 ↗
29. ACS Nano · 2016 · 10 · 977610.1021/acsnano.6b05944 ↗
30. Nature · 2016 · 536 · 31210.1038/nature18306 ↗
31. Science · 2017 · 355 · 128810.1126/science.aal4211 ↗
32. J. Phys. Chem. Lett. · 2018 · 9 · 589110.1021/acs.jpclett.8b02653 ↗
33. J. Phys. Chem. Lett. · 2018 · 9 · 143410.1021/acs.jpclett.8b00201 ↗
34. AIP Adv. · 2018 · 8 · 02510810.1063/1.5020836 ↗
35. Phys. Rev. B · 2015 · 92 · 04541410.1103/physrevb.92.045414 ↗
36. Adv. Mater. · 2018 · 30 · 170405510.1002/adma.201704055 ↗
37. Acta Crystallogr., Sect. B: Struct. Sci. · 2007 · 63 · 73510.1107/s0108768107031758 ↗
38. New J. Chem. · 2008 · 32 · 173610.1039/b805417g ↗
39. Dalton Trans. · 2012 · 41 · 114610.1039/c0dt01805h ↗
40. Sci. Rep. · 2015 · 5 · 1663410.1038/srep16634 ↗
41. Chem. Mater. · 2016 · 28 · 285210.1021/acs.chemmater.6b00847 ↗
42. Science · 1971 · 172 · 56710.1126/science.172.3983.567 ↗
43. Cryst. Growth Des. · 2015 · 15 · 515710.1021/acs.cgd.5b01188 ↗
44. Phys. Rev. Mater. · 2018 · 2 · 06460510.1103/physrevmaterials.2.064605 ↗
45. 2018
46. Phys. Rev. Mater. · 2018 · 2 · 03400110.1103/physrevmaterials.2.034001 ↗
47. J. Mater. Chem. A · 2016 · 4 · 1599710.1039/c6ta04949d ↗
48. J. Am. Chem. Soc. · 2017 · 139 · 1111710.1021/jacs.7b04981 ↗
49. Nat. Commun. · 2014 · 5 · 358610.1038/ncomms4586 ↗
50. Sci. Adv. · 2016 · 2 · e160115610.1126/sciadv.1601156 ↗
51. Energy Environ. Sci. · 2016 · 9 · 15510.1039/c5ee02925b ↗
52. J. Mater. Chem. C · 2017 · 5 · 277110.1039/c7tc00366h ↗
53. ACS Energy Lett. · 2017 · 2 · 41710.1021/acsenergylett.6b00659 ↗
54. J. Am. Chem. Soc. · 2017 · 139 · 1863210.1021/jacs.7b10223 ↗
55. Chem. Mater. · 2017 · 29 · 1008810.1021/acs.chemmater.7b03851 ↗
56. J. Mater. Chem. C · 2016 · 4 · 463010.1039/c6tc01360k ↗
57. Adv. Funct. Mater. · 2018 · 28 · 170700610.1002/adfm.201707006 ↗