journal article·2026-06-01Open access

Depth-resolved dielectric function analysis of oxygen-deficient WO3-x thin films via graded ellipsometric modeling

Hao Chen, Alessandro Chiasera, Alice Carlotto, Stefano Varas, Marco Faverzani, Paolo Biagioni, Silvia Maria Pietralunga

AIP Advances· Volume 16· Issue 6

Abstract

This work presents an investigation of the complex dielectric function of oxygen-deficient WO3-x thin films prepared by non-reactive radio-frequency sputtering and its evolution upon post-deposition annealing in air, using Variable-Angle Spectroscopic Ellipsometry. A depth-dependent graded optical model was developed to resolve spatial variations in the dielectric response arising from oxidation-induced compositional gradients. This approach provides a more accurate physical representation than conventional models, which assume a uniform dielectric function throughout the film. The as-deposited films exhibit strong sub-bandgap absorption, likely attributable to defect states associated with oxygen vacancies. Annealing at 400–500 °C facilitates oxygen incorporation that progressively suppresses the defect-related optical loss near the film surface. Transparency in the visible and near-infrared ranges is achieved within a depth of ∼70 nm, resulting in a homogeneous optical response. In thicker films, deeper regions remain oxygen-deficient due to the limited oxygen diffusion length, resulting in a continuous depth-dependent gradient of the dielectric function that is captured by the fitting model presently developed. The graded model can be used as a quality control tool for the fine-tuning of post-deposition annealing processes, and it provides a robust and physically grounded framework for describing the optical response of oxide thin films with spatially varying defect distributions.
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Research context

OpenAlex topics: Transition Metal Oxide Nanomaterials · Optical Coatings and Gratings · Optical Polarization and Ellipsometry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Dipartimento di Fisica, Politecnico di Milano 1 , Piazza L. da Vinci, 32, 20133 Milano,

CNST@PoliMi, Istituto Italiano di Tecnologia (IIT) 2 , Via Rubattino, 81, 20134 Milano,

Institute for Photonics and Nanotechnologies (IFN)—National Research Council (CNR) CSMFO Lab. 3 , Via alla Cascata 56/C, 38123 Trento,

Fondazione Bruno Kessler (FBK)—Centro Sensors & Devices (S&D) 4 , Via Sommarive, 18, 38123 Trento,

Fondazione Bruno Kessler (FBK)—Center for Sustainable Energy—HyRES Unit 5 , Via Sommarive, 18, 38123 Trento,

Institute for Photonics and Nanotechnologies (IFN)—National Research Council (CNR) 6 , Piazza L. da Vinci, 32, 20133 Milano,

Funding

Ministero dell’Università e della Ricerca · Ministero dell’ambiente e della sicurezza energetica

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