journal article·2026-03-01Open access

Direct heteroepitaxy of β -Ga2O3 on 4H-SiC as a prospective foundation for vertical power devices

Dominic Lane, Daniel A. Lamb, Indraneel Sanyal, Donghoon Chang, Sijia Fu, Ciaran P. Llewelyn, Petar B. Atanackovic

AIP Advances· Volume 16· Issue 3

Abstract

We report the successful metal-organic-chemical-vapor deposition-based direct heteroepitaxy of β-Ga2O3 on 4H-SiC (GOSiC) suited for vertical device applications by eliminating the need for interface or buffer layers. We systematically vary the VI/III ratio and growth temperature to study the structural and electrical performance. Structural characterization via transmission electron microscopy, x-ray diffraction, and atomic force microscopy confirms abrupt interfaces, good crystallinity, and low surface roughness. Secondary ion mass spectroscopy analysis demonstrates growth window optimization for low carbon incorporation and suppressed out-diffusion of substrate elements. Ni Schottky barrier diodes fabricated on these films exhibit reverse current characteristics up to 1.18 MV/cm for a 1 mA cm−2 reverse leakage without field management techniques. These results match or surpass those reported for state-of-the-art homoepitaxy on comparable device structures and, to our knowledge, represent the highest breakdown field for β-Ga2O3 heteroepitaxy reported to date. This establishes GOSiC as a promising scalable, thermally managed platform for high-voltage vertical device applications.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Ga2O3 and related materials · GaN-based semiconductor devices and materials · Thin-Film Transistor Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Silanna Semiconductor Pty Ltd. 1 , Adelaide,

The University of Adelaide 2 , Adelaide,

Centre for Integrative Semiconductor Materials (CISM), Swansea University 3 , Swansea,

Aixtron Ltd. 4 , Cambridge,

References (24)

Show source-provided references
1. A review of Ga2O3 materials, processing, and devices10.1063/1.5006941 ↗
2. Study of thermal annealing on gallium oxide heteroepitaxial layers grown on SiC for vertical Schottky barrier diodes applications10.1016/j.apsadv.2024.100661 ↗
3. Thermal-mechanical perspectives on hydrophilic- and surface-activated-bonding Si/SiC interfaces for SOI’s thermal management enhancement10.1063/5.0253834 ↗
4. Enhanced phonon transmission at thin-film Si on diamond interface via microtransfer printing10.26599/nr.2025.94908110 ↗
5. A novel AlN/β-Ga2O3 high electron mobility transistor with 2 kV and 600 GHz operation10.1007/s00542-025-05927-9 ↗
6. Adherent β-Ga2O3 thin films on single crystal diamond (001) substrates enabled by (AlxGa1−x)2O3 buffer layers10.1063/5.0276605 ↗
7. High power density gallium nitride radio frequency transistors via enhanced nucleation in heteroepitaxy10.1038/s41467-025-67248-9 ↗
8. Barrier-layer optimization for enhanced gan-on-diamond device cooling10.1021/acsami.7b08961 ↗
9. Band alignment and electronic structure of β -Ga2O3 (−201) grown on Si- and C-faces of 4H–SiC substrates10.1016/j.vacuum.2024.113164 ↗
10. Decomposition mechanisms of trimethylgallium10.1016/0022-0248(90)90891-N ↗
11. Demonstration of MOCVD-based in-situ etching of β-Ga2O3 using tega10.1063/5.0195361 ↗
12. Structure and chemistry of passivated SiC/SiO2 interfaces10.1063/1.4951677 ↗
13. Active and passive oxidation of SiC and Si3N410.1111/j.1151-2916.1993.tb03684.x ↗
14. Semiconductor device
15. Wet etch clean-up of plasma damage for 1.68 kv breakdown in NiO/β-Ga2O3 chlorine-etched PN diodes10.1116/6.0004289 ↗
16. Thermodynamics of Ga2O3 heteroepitaxy and material growth via metal organic chemical vapor deposition10.1021/acsaelm.4c00535 ↗
17. Improved performance of lateral β-Ga2O3 Schottky barrier diodes by nitrogen thermal annealing10.1016/j.apsadv.2025.100744 ↗
18. The role of carbon and C–H neutralization in MOCVD β-Ga2O3 using TMGa as precursor10.1063/5.0153626 ↗
19. Oxygen vacancies and donor impurities in β-Ga2O310.1063/1.3499306 ↗
20. Origin of photoluminescence in β-Ga2O310.1103/PhysRevB.97.115163 ↗
21. Reproducible NiO/Ga2O3 vertical rectifiers with breakdown voltage >8 kv10.3390/cryst13060886 ↗
22. Fabrication of Ga2O3 Schottky barrier diode and heterojunction diode by MOCVD10.3390/ma15238280 ↗
23. Electrical characteristics of vertical Ni/β-Ga2O3 Schottky barrier diodes at high temperatures10.1149/2.0041702jss ↗
24. Over 1 Gw/cm2 vertical Ga2O3 Schottky barrier diodes without edge termination10.1109/LED.2021.3133866 ↗