journal article·2015-12-01Open access

Electrical characterization of fluorinated benzothiadiazole based conjugated copolymer – a promising material for high-performance solar cells

J. Toušek, J. Toušková, Z. Remeš, R. Chomutová, J. Čermák, M. Helgesen, J. E. Carlé, F. C. Krebs

AIP Advances· Volume 5· Issue 12

Abstract

Measurements of electrical conductivity, electron work function, carrier mobility of holes and the diffusion length of excitons were performed on samples of conjugated polymers relevant to polymer solar cells. A state of the art fluorinated benzothiadiazole based conjugated copolymer (PBDTTHD − DTBTff) was studied and benchmarked against the reference polymer poly-3-hexylthiophene (P3HT). We employed, respectively, four electrode conductivity measurements, Kelvin probe work function measurements, carrier mobility using charge extraction by linearly increasing voltage (CELIV) measurements and diffusion length determinaton using surface photovoltage measurements.
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Thin-Film Transistor Technologies

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Affiliations

Charles University in Prague 1 , Faculty of Mathematics and Physics, V Holešovičkách 2, 182 00 Prague 8, Czech Republic

Institute of Physics of the Academy of Sciences 2 , Cukrovarnická 10, 162 53 Prague 6, Czech Republic

Technical University of Denmark 3 Department of Energy Conversion and Storage, , Frederiksborgvej 399, DK-4000 Roskilde, Denmark

Funding

CS Fund · European Cooperation in Science and Technology · Ministerstvo Školství, Mládeže a Tělovýchovy · Grantová Agentura České Republiky

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