journal article·2019-09-01Open access

Magnetically recyclable Cr complex for the dehydration of glucose to 5-HMF in acidic task specific ionic liquid

Fei Fu, Minggui Shen, Shibin Shang, Zhanqian Song, Liang Wang

AIP Advances· Volume 9· Issue 9

Abstract

Magnetically recyclable Cr complex was synthesized by immobilizing Cr3(CH3COO)7(OH)2 onto the surface of amino modified Fe3O4 particles. The structure of the catalyst was well characterized by Fourier transform infrared (FT-IR), Transmission electron microscope (TEM), Inductively coupled plasma atomic emission spectroscopy (ICP-AES), Energy dispersive X-ray spectroscopy (EDX), Thermal gravity analysis (TG-ATG), Wide-angle X-ray Diffractometry (XRD) and Vibrating Sample Magnetometer (VSM). The prepared catalyst showed good catalytic performance in the conversion of glucose to HMF in acidic task specific ionic liquid (TSIL). Moreover, the catalyst could be magnetically recovered and for successive six runs without significant decrease in its activity.
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Research context

OpenAlex topics: Catalysis for Biomass Conversion · Metal-Organic Frameworks: Synthesis and Applications · Chemical Synthesis and Reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Key Laboratory of Biomass Energy and Material, National Engineering Laboratory for Biomass Chemical Utilization, Key and Open Laboratory of Forest Chemical Engineering, State Forestry Administration 1 , Nanjing 210042, Jiangsu Province, China

Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Nanjing Forestry University 2 , Nanjing 210037, People’s Republic of China

Institute of New Technology of Forestry, Chinese Academy of Forestry 3 , Beijing 100091, China

School of Petrochemical Engineering, Jiangsu Key Laboratory of Advanced Catalytic Materials & Technology, Changzhou University 4 , Changzhou 213164, P. R. China

Funding

Jiangsu key laboratory for biomass energy and material · China Postdoctoral Science Foundation · Natural Science Foundation of Jiangsu Province

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