journal article·2022-03-01Open access

An advanced physical modeling of adsorption mechanism of pharmaceutical compound on a biochar

Manel Ben Yahia

AIP Advances· Volume 12· Issue 3

Abstract

In this paper, the adsorption process of a pharmaceutical compound (tetracycline: TC) on a biochar was theoretically analyzed. The adsorbent was activated via two different methods (impregnation method and dry mixing method). The adsorption mechanism of TC was understood through an analysis of double-layer model parameters, suggesting that the adsorption of TC can be achieved via formation of two layers on both adsorbents. This modeling showed that this aggregation process was present and absent for the adsorption systems TC–biochar impregnation method (BCI) and TC–biochar dry mixing method (BCD), respectively. Comparatively, it was demonstrated that both adsorbents were characterized by excellent adsorption capacities and they can be alternatives to remove TC. The interactions between TC–BCD, TC–BCI, and TC–TC were estimated by an adsorption energy calculation at different temperatures. Overall, the interpretation of the model parameters provided plausible insights into the adsorption mechanism.
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Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Coagulation and Flocculation Studies · Pharmaceutical and Antibiotic Environmental Impacts

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Physics Department, College of Science and Arts, King Abdulaziz University , P.O. Box 344, Rabigh 21911, Saudi Arabia

References (27)

Show source-provided references
1. Occurrence and removal of transformation products of PPCPs and illicit drugs in wastewaters: A review10.1016/j.scitotenv.2014.10.021 ↗
2. Occurrences and removal of pharmaceuticals and personal care products (PPCPs) in drinking water and water/sewage treatment plants: A review10.1016/j.scitotenv.2017.04.102 ↗
3. Psychiatric pharmaceuticals in the environment10.1016/j.chemosphere.2009.09.021 ↗
4. Pharmaceuticals and personal care products (PPCPs) in the freshwater aquatic environment10.1016/j.emcon.2016.12.004 ↗
5. Selective adsorption of uranyl and potentially toxic metal ions at the core-shell MFe2O4-TiO2 (M=Mn, Fe, Zn Co, or Ni) nanoparticles10.1016/j.jhazmat.2018.11.076 ↗
6. Fate of antibiotics during municipal water recycling treatment processes10.1016/j.watres.2010.06.020 ↗
7. Adsorption of pharmaceuticals from water and wastewater using nonconventional low-cost materials: A review10.1021/acs.iecr.7b05137 ↗
8. Adsorption of diclofenac from aqueous solution using Cyclamen persicum tubers based activated carbon (CTAC)10.1016/j.jaubas.2014.11.002 ↗
9. Adsorption of tetracycline fom wastewater by using Pistachio shell coated with ZnO nanoparticles: Equilibrium, kinetic and isotherm studies10.1016/j.aej.2019.08.006 ↗
10. Adsorption and photocatalytic degradation of tetracycline hydrochloride using a palygorskite supported Cu2O–TiO2 composite10.1016/j.clay.2015.10.033 ↗
11. Removal of antibiotics in wastewater: Effect of hydraulic and solid retention times on the fate of tetracycline in the activated sludge process10.1021/es050006u ↗
12. Magnetic microsphere to remove tetracycline from water: Adsorption, H2O2 oxidation and regeneration10.1016/j.cej.2017.07.054 ↗
13. Effective removal of tetracycline from aqueous solution using activated carbon prepared from tomato (Lycopersicon esculentum Mill.) industrial processing waste10.1016/j.ecoenv.2016.05.001 ↗
14. Modification of biochar derived from sawdust and its application in removal of tetracycline and copper from aqueous solution: Adsorption mechanism and modelling10.1016/j.biortech.2017.08.178 ↗
15. Sorptive removal of tetracycline from water by palygorskite10.1016/j.jhazmat.2008.09.113 ↗
16. Mechanisms for strong adsorption of tetracycline to carbon nanotubes: A comparative study using activated carbon and graphite as adsorbents10.1021/es803268b ↗
17. Adsorption and removal of tetracycline antibiotics from aqueous solution by graphene oxide10.1016/j.jcis.2011.11.015 ↗
18. Adsorptive removal of antibiotics from aqueous solution using carbon materials10.1016/j.chemosphere.2016.03.083 ↗
19. Systematic study of synergistic and antagonistic effects on adsorption of tetracycline and copper onto a chitosan10.1016/j.jcis.2009.11.049 ↗
20. Tetracycline adsorption on montmorillonite: pH and ionic strength effects10.1016/j.clay.2007.08.003 ↗
21. Preparation of porous biochar based on pharmaceutical sludge activated by NaOH and its application in the adsorption of tetracycline10.1016/j.jcis.2020.12.014 ↗
22. Monolayer and multilayer adsorption of pharmaceuticals on activated carbon: Application of advanced statistical physics models10.1016/j.molliq.2019.03.101 ↗
23. Enhanced removal of tetracycline using modified sawdust: Optimization, isotherm, kinetics, and regeneration studies10.1016/j.psep.2018.04.007 ↗
24. Parameter optimization of tetracycline removal by vanadium oxide nano cuboids10.1016/j.colsurfa.2021.126460 ↗
25. Combined minimum-run resolution IV and central composite design for optimized removal of tetracycline drug over metal–organic framework-templated porous carbon10.3390/molecules24101887 ↗
26. Effective adsorption of dyes on an activated carbon prepared from carboxymethyl cellulose: Experiments, characterization and advanced modelling10.1016/j.cej.2020.128116 ↗
27. Adsorption of ibuprofen on organo-sepiolite and on zeolite/sepiolite heterostructure: Synthesis, characterization and statistical physics modeling10.1016/j.cej.2019.04.138 ↗