Research on a material for hydrogen purifying and flux controlling with application to space active hydrogen-masers
Source abstract
Abstract
The Space Active Hydrogen-Maser (SAHM) can be used for the Space Very Long Baseline Interferometry Project to improve the resolution of the space astronomical telescope. The standard frequency signals provided by the SAHM have their stability dependent on the flux of effective H atoms. Therefore, a nickel (Ni) tube, one end closed, has been designed in this paper for the SAHM as a hydrogen (H2) purification and flux control device. Mechanisms of the H2 purification and flux control by a Ni tube were studied. H2 flux and ΔU, as a function of an input current, are given by experimental analyses. The diffusion activation energy of atomic H is much less than that of other atoms under the same conditions in Ni. The H atoms reversibly diffuse in Ni, and their diffusion speed has a high response to temperature. Experimental research shows that when the temperature of the tube was changed (from 27 to 700 °C), by an input heating electrical current (from 0 to 3.5 A), the H2 flux varied from 0 to 9.18 × 10−10 mol/s and no change in the phase structure of Ni. The data of flux should be useful for the frequency stability performance research of the SAHM. In addition, no phase change of the material indicates a stable performance of the tube for H-purifying and flux controlling. Finally, the above advantages make it a promising candidate for the reliability of the SAHM.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Spacecraft and Cryogenic Technologies · Astrophysics and Star Formation Studies · Advanced Thermodynamic Systems and Engines
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Materials Science and Engineering, Shanghai University 1 , Shanghai 200072, China
Shanghai Astronomical Observatory, Chinese Academy of Sciences 2 , Shanghai 200030, China
Funding
National Natural Science Foundation of China · Chinese Academy of Sciences
References (22)
Show source-provided references
1. 2013 · 87
2. 2016 · 180
3. 2010 · 4
4. The atomic hydrogen maser oscillator10.1088/0026-1394/42/3/s09 ↗
5. 1980 · 3
6. Theory of the hydrogen maser10.1103/physrev.126.603 ↗
7. 2007 · 6
8. 1986
9. Pressure swing adsorption/membrane hybrid processes for hydrogen purification with a high recovery10.1007/s11705-016-1567-1 ↗
10. High purity hydrogen: Guidelines to select the most suitable purification technology10.17265/2328-2223/2017.05.005 ↗
11. Investigating PSA, VSA, and TSA methods in SMR unit of refineries for hydrogen production with fuel cell specification10.1016/j.seppur.2016.11.030 ↗
12. The diffusion and trapping of hydrogen along the grain boundaries in polycrystalline nickel10.1016/j.scriptamat.2011.09.036 ↗
13. DOSE materials, IO metal, CAO Sciences, rapid hydrogen transportation along grain boundary in nickel10.1007/s40195-014-0102-y ↗
14. Hydrogen diffusion in nanocrystalline nickel indicating a structural change within the grain boundaries after annealing10.1016/s1359-6462(97)00225-x ↗
15. Segregation of hydrogen and vacancies at the Σ5(210)[001] symmetric tilt grain boundary in Ni and influence on cohesion10.1088/1361-651x/abdc6a ↗
16. Grain size and grain-boundary effects on diffusion and trapping of hydrogen in pure nickel10.1016/j.actamat.2012.09.004 ↗
17. Segregation of hydrogen to defects in nickel using first-principles calculations: The case of self-interstitials and cavities10.1016/j.jallcom.2014.05.094 ↗
18. Diffusion and solubility of hydrogen in single crystals of nickel and nickel—Vanadium alloy10.1063/1.1840860 ↗
19. Diffusion and solubilization of hydrogen in Ni-base single crystal superalloys10.3724/sp.j.1037.2012.00261 ↗
20. Temperature-dependent diffusion coefficients from ab initio computations: Hydrogen, deuterium, and tritium in nickel10.1103/physrevb.77.134305 ↗
21. 2005
22. Numerical simulation of hydrogen atom transport in thick nickel membrane using semi-empirical quantum model10.1016/j.ijhydene.2009.10.023 ↗