journal article·2021-11-01Open access

Fabrication of externally wetted emitter for ionic liquid electrospray thruster by low-speed wire cutting combined with electrochemical etching

Senwen Xue, Li Duan, Qi Kang

AIP Advances· Volume 11· Issue 11

Abstract

The micro-newton thrust generated by an ionic liquid electrospray thruster (ILET) can be used for drag-free control, attitude precise control, networking, and formation flight of micro-nano-satellites or spacecraft. Fabrication of high-quality emitters is one of the key technologies for the application of ILETs. A new method for fabricating externally wetted emitters is presented in this article. This method uses low-speed wire cutting (LSWC) combined with electrochemical etching, and the externally wetted emitter is fabricated in three steps. First, the tungsten cuboid is shaped by LSWC to get the geometry of the emitter. Second, the emitter is cleaned by superacid to remove the oxide layer that critically prevents the ionic liquid from wetting the emitter. Finally, microchannels are etched on the emitter surface by electrochemical etching. The tungsten emitter fabricated by the above-mentioned steps can obtain excellent wettability, and its microchannel can reduce the contact angle between the wall and the ionic liquid and enhance the capillary force that promotes the ionic liquid to climb along the emitter. The ionic liquid is spread into a uniform liquid film on the emitter surface to ensure a stable and continuous flow supply so that the thruster can work in pure ionic emission mode for a long time with low noise, high resolution, and a high thrust power ratio. The quantitative and qualitative analysis of all elements before and after the pickling emitter proves the feasibility of removing the oxide layer. The morphology features of the emitter are measured and observed using a metallographic microscope and profilometer, including the microchannel structure and its size and tip size and the thickness of the liquid film. Through repeated observation and evaluation, the etching parameters are recorded, including the amplitude and frequency of AC voltage, the etching time, the depth of emitter immersion in the solution, and the concentration of NaOH solution. In order to compare the performance of an externally wetted emitter and a porous emitter, the same process is used to fabricate two kinds of emitters. The conclusions on beam current, the resolution and noise of beam current, ignition reliability, and emission time are summarized during the emission testing. The emission tests indicate that the externally wetted emitter exhibits outstanding performance, which depends on its better wettability and the fact that the microchannels are not easily blocked by the products of electrochemical reaction.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Electrohydrodynamics and Fluid Dynamics · Mass Spectrometry Techniques and Applications · Microfluidic and Capillary Electrophoresis Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Microgravity, Institute of Mechanics, Chinese Academy of Sciences , Beijing 100190, People’s Republic of China and , Beijing 100049, People’s Republic of China

School of Engineering Sciences, University of Chinese Academy of Sciences , Beijing 100190, People’s Republic of China and , Beijing 100049, People’s Republic of China

Funding

National Natural Science Foundation of China · The Strategic Priority Research Program of the Chinese Academy of Science

References (55)

Show source-provided references
1. 1991
2. A liquid caesium field ion source for space propulsion10.1088/0022-3727/17/12/014 ↗
3. Micronewton indium FEEP thrusters
4. Emission characteristics of passively fed electrospray microthrusters with propellant reservoirs10.2514/1.a33531 ↗
5. Ionic liquid ion sources as a unique and versatile option in FIB applications10.1016/j.mee.2010.11.042 ↗
6. Development of ion sources from ionic liquids for microfabrication10.1116/1.3432125 ↗
7. Development of ionic liquid ion source with porous emitter for surface modification10.1016/j.nimb.2013.05.065 ↗
8. High-resolution mass spectrometer for liquid metal ion sources10.1063/1.4822275 ↗
9. 2007
10. Ionic liquid ion sources: Characterization of externally wetted emitters10.1016/j.jcis.2004.08.132 ↗
11. A planar array of micro-fabricated electrospray emitters for thruster applications10.1109/jmems.2006.879710 ↗
12. A microfabricated planar electrospray array ionic liquid ion source with integrated extractor10.1109/jmems.2009.2015475 ↗
13. Taylor cones of ionic liquids from capillary tubes as sources of pure ions: The role of surface tension and electrical conductivity10.1063/1.2783769 ↗
14. Integrated out-of-plane nanoelectrospray thruster arrays for spacecraft propulsion10.1088/0960-1317/19/4/045019 ↗
15. Microfabricated electrospray emitter arrays with integrated extractor and accelerator electrodes for the propulsion of small spacecraft10.1088/0960-1317/24/7/075011 ↗
16. Miniaturized electrospray thrusters10.1109/tps.2017.2755373 ↗
17. Electrospray propulsion based on emitters microfabricated in porous metals10.2514/1.50037 ↗
18. Electrochemical micromachining on porous nickel for arrays of electrospray ion emitters10.1109/jmems.2012.2227951 ↗
19. On the manufacturing and emission characteristics of dielectric electrospray sources
20. Ion field-evaporation from ionic liquids infusing carbon xerogel microtips10.1063/1.4927481 ↗
21. Comparing direct and indirect thrust measurements from passively fed ionic electrospray thrusters10.2514/1.b35836 ↗
22. Porous materials for ion-electrospray spacecraft microengines10.1061/(asce)nm.2153-5477.0000121 ↗
23. Colloid micro-Newton thruster development for the ST7-DRS and LISA missions
24. Component-level development and testing of a colloid micro-thruster (CMT) system for the LISA mission
25. LISA colloid microthruster technology development plan and progress
26. Colloid microthruster flight performance results from space technology 7 disturbance reduction system
27. Externally wetted ionic liquid thruster
28. Ionic liquid ion sources: Suppression of electrochemical reactions using voltage alternation10.1016/j.jcis.2004.07.037 ↗
29. Analysis of the electrospray plume from the EMI-Im propellant externally wetted on a tungsten needle
30. Effect of tip curvature on ionic emissions from Taylor cones of ionic liquids from externally wetted tungsten tips10.1063/1.3073873 ↗
31. Liquid gold ion source10.1116/1.570316 ↗
32. Low-energy ion optical system with a liquid-metal ion source for imaging and processing solid structures10.1016/0304-3991(93)90022-p ↗
33. Note: Fabrication of roughened tips for liquid metal ion sources10.1063/1.4985635 ↗
34. A novel variable mode emitter for electrospray thrusters
35. A simple technique for making very fine, durable dissecting needles by sharpening tungsten wire electrolytically
36. Electrochemical preparation of tungsten tips for a scanning tunneling microscope10.1063/1.1146996 ↗
37. A development in the preparation of sharp scanning tunneling microscopy tips10.1063/1.1144140 ↗
38. Electrochemically etched nickel tips for spin polarized scanning tunneling microscopy10.1063/1.1311936 ↗
39. Preparation and characterization of STM tips for electrochemical studies10.1063/1.1140590 ↗
40. An improved control technique for the electrochemical fabrication of scanning tunneling microscopy microtips10.1063/1.1148032 ↗
41. Fabrication of porous emitters for ionic liquid ion source by wire electrical discharge machining combined with electrochemical etching10.1063/1.5099512 ↗
42. Study on the emitter infiltration of needle-capillary ionic liquid electrospray thruster10.1063/5.0040081 ↗
43. The hydrodynamics of liquid metal ion sources10.1063/1.93100 ↗
44. The effects of flow impedance on the current-voltage characteristics of liquid-metal ion sources10.1088/0022-3727/30/13/017 ↗
45. Disintegration of water drops in an electric field10.1098/rspa.1964.0151 ↗
46. The current emitted by highly conducting Taylor cones10.1017/s0022112094003472 ↗
47. Breakup of diminutive Rayleigh jets10.1063/1.3524533 ↗
48. Electrokinetic effects in the breakup of electrified jets: A volume-of-fluid numerical study10.1016/j.ijmultiphaseflow.2014.12.005 ↗
49. Electrostatic spraying of liquids in cone-jet mode10.1016/0304-3886(89)90081-8 ↗
50. How much charge is there on a pulsating Taylor cone?10.1063/1.2266889 ↗
51. Source of heavy molecular ions based on Taylor cones of ionic liquids operating in the pure ion evaporation regime10.1063/1.1598281 ↗
52. On the evaporation of small ions from charged droplets10.1063/1.432536 ↗
53. Energy properties of an EMI-Im ionic liquid ion source10.1088/0022-3727/39/1/020 ↗
54. Mass spectrometric analysis of colloid thruster ionic emission from selected propellants10.2514/1.9690 ↗
55. Current rectification for transport of room-temperature ionic liquids through conical nanopores10.1021/acs.jpcc.5b11522 ↗