A one-dimensional stochastic approach to the study of cyclic voltammetry with adsorption effects
Source abstract
Abstract
In this study, a one-dimensional stochastic model based on the random walk approach is used to simulate cyclic voltammetry. The model takes into account mass transport, kinetics of the redox reactions, adsorption effects and changes in the morphology of the electrode. The model is shown to display the expected behavior. Furthermore, the model shows consistent qualitative agreement with a finite difference solution. This approach allows for an understanding of phenomena on a microscopic level and may be useful for analyzing qualitative features observed in experimentally recorded signals.
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Research context
OpenAlex topics: Electrochemical Analysis and Applications · Molecular Junctions and Nanostructures · Spectroscopy and Quantum Chemical Studies
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Affiliations
The Ohio State University The Department of Mechanical and Aerospace Engineering, , 201 W 19 th Avenue, Columbus, Ohio 43210 USA
References (28)
Show source-provided references
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