Quantum sensing effect of electron tunneling in DQD/analyte complex
Source abstract
Abstract
We investigate electron tunneling between quantum dots and molecules to propose a quantum sensor. This sensor consists of double quantum dots (DQD) with energy levels specifically tailored to mirror those of the target analyte. By analyzing the spectral distribution of electron localizations in the DQD system, we can delineate the analyte’s spectrum and deduce its composition by comparing it with a reference sample. To understand electron tunneling dynamics within the DQD/analyte complex, we performed three-dimensional computational modeling applying the effective potential approach to the InAs/GaAs heterostructure. In this modeling, we mimicked the analyte spectrum by utilizing a quantum well characterized by a quasi-discrete spectrum. Our calculations reveal the inherent potential of utilizing this method as a highly sensitive and selective sensor.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Quantum and electron transport phenomena · Semiconductor Quantum Structures and Devices · Molecular Junctions and Nanostructures
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
CREST, North Carolina Central University 1 , Durham, North Carolina 27707, USA
Department of Chemical Engineering, University of Rhode Island 2 , Kingston, Rhode Island 02881, USA
Funding
Science and Technology Directorate · US National Science Foundation · National Security Administration
References (36)
Show source-provided references
1. Single-molecule tunneling sensors for nitrobenzene explosives10.1021/acs.analchem.2c01592 ↗
2. Construction of biomolecular sensors based on quantum dots10.1039/c6ra20499f ↗
3. Quantum-dot-based photoelectrochemical sensors for chemical and biological detection10.1021/am3028662 ↗
4. Nanostructure based methods for detection structure determination separation transport extraction and control of chemical and biochemical material
5. Detection methods and detection devices based on the quantum confinement effects,” U.S. patent 8,262,998
6. Subpicosecond photoinduced hole transfer from a CdS quantum dot to a molecular acceptor bound through an exciton-delocalizing ligand10.1021/acsnano.6b02814 ↗
7. Nanosensing backed by the uncertainty principle10.1155/2016/3794109 ↗
8. Electron transfer from the barrier in InAs/GaAs quantum dot-well structure10.1016/j.physe.2019.113629 ↗
9. Effect of double quantum dot asymmetry on electron localization10.1142/s0217984923420058 ↗
10. SnO2 nanoribbons as NO2 sensors: Insights from first principles calculations10.1021/nl034235v ↗
11. Electronic processes within quantum dot-molecule complexes10.1021/acs.chemrev.6b00102 ↗
12. Thermoelectricity in tunneling nanostructures10.1103/physrevb.92.155431 ↗
13. Thermopower for a molecule with vibrational degrees of freedom10.1016/j.physleta.2014.01.054 ↗
14. Quantum dots synthetization and future prospect applications10.1515/ntrev-2021-0118 ↗
15. 2019
16. Coulomb blockade and the Kondo effect in single-atom transistors10.1038/nature00791 ↗
17. Coulomb blockade in monolithic and monocrystalline Al-Ge-Al nanowire heterostructures10.1063/1.5126088 ↗
18. Impact of the gate geometry on adiabatic charge pumping in InAs double quantum dots10.1039/d2na00372d ↗
19. A tunable Kondo effect in quantum dots10.1126/science.281.5376.540 ↗
20. Single-shot read-out of an individual electron spin in a quantum dot10.1038/nature02693 ↗
21. Charge detection in an array of CMOS quantum dots10.1103/physrevapplied.14.024066 ↗
22. Observation of single-electron charging effects in small tunnel junctions10.1103/physrevlett.59.109 ↗
23. Electro sensors based on quantum dots and their applications in diagnostic medicine
24. Nanoscale electric-field imaging based on a quantum sensor and its charge-state control under ambient condition10.1038/s41467-021-22709-9 ↗
25. Electric-field sensor based on a double quantum dot in a microcavity10.1134/s1063782617090214 ↗
26. Magnetic field sensing using a driven double quantum dot10.1016/j.physe.2009.11.138 ↗
27. GaAs quantum dot thermometry using direct transport and charge sensing10.1007/s10909-014-1169-6 ↗
28. DNA-conjugated quantum dot nanoprobe for high-sensitivity fluorescent detection of DNA and micro-RNA10.1021/am404811j ↗
29. A sensitive biosensor based on optical bistability in a semiconductor quantum dot-DNA nanohybrid10.1088/1361-6463/aaec48 ↗
30. 1996
31. Vibronic coupling in molecules and in solids10.1002/chem.200390062 ↗
32. Bersuker · 2010 · 32410.1002/9780470573051.ch7 ↗
33. Tunneling-barrier controlled excitation transfer in hybrid quantum dot-quantum well nanostructures10.1063/1.3493240 ↗
34. Modelling of InAs/GaAs quantum ring capacitance spectroscopy in the non-parabolic approximation10.1103/physrevb.73.205332 ↗
35. InGaAs/GaAs quantum dots within an effective approach10.1016/j.physe.2009.04.002 ↗
36. 2005 · 168