A numerical study for dielectric constant profile of aqueous solvent in ionic solution radiated by high-intensity electric pulses

In this paper, a mathematical physics model is set up to study dielectric constant profile of aqueous solvent in ionic solution, to revise Brownian dynamics simulation in ionic solution by considering time-variant dielectric constant profile with change in ion positions, and to study the effect of high-intensity electric pulses on the profile. The validation of the model is confirmed with verification calculations. By means of the proposed model, dielectric constant profiles in calcium chloride and sodium chloride solutions and their response to pulses are simulated. Based on numerical results, dielectric constants of aqueous solvent spatially vary instead of being the same value in ionic solutions. And the profiles are variant with time due to ion motion in solutions. From the profiles, overall dielectric constant in calcium chloride solution is lower than that in sodium chloride solution. And overall dielectric constant decreases with increment of solution concentration. In addition, the results show that influence on the profiles depends on solution concentration and field intensity of the pulse. The profile in solutions with low concentration is more vulnerable to the pulse than that with high concentration. And overall dielectric constant decreases dramatically as field intensity increases. Those understandings provide basis for application of pulses in biomedical engineering at the molecular level. Meanwhile, pulse radiation provides a potential way to constrain water molecules at room temperature reflected by significantly reducing dielectric constant, and to lower absorption loss of electromagnetic field in millimeter and far infrared band.