journal article·2018-07-01Open access

Effect of temperature on foamability using a thermoresponsive polymer

Matthew Jackman, Adrien Bussonnière, Hin Long Leung, Zhenghe Xu, Peichun Amy Tsai, Qingxia Liu

AIP Advances· Volume 8· Issue 7

Abstract

We experimentally examine foam dynamics and foamability using a thermoresponsive polymer, Poly(n-isopropylacrylamide) or PNIPAM. Under a constant gas injection, our results show that temperature significantly affects the foam height produced. A stable foam was observed at room temperature while unstable at temperature above the lower critical solution temperature. Analysis of the foam structure reveals an important increase in the coalescence rate at high temperature, thereby suggesting a change of the air-water interface properties with the temperature. The findings demonstrate the controlling ability of the PNIPAM polymer to produce thermoresponsive foams, offering beneficial applications for foaming processes and mineral flotation.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Pickering emulsions and particle stabilization · Surfactants and Colloidal Systems · Enhanced Oil Recovery Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical and Materials Engineering, University of Alberta 1 , Edmonton, Alberta T6G 1H9, Canada

Department of Mechanical Engineering, University of Alberta 2 , Edmonton, Alberta T6G 1H9, Canada

Funding

Canadian Center for Clean Coal/Carbon and Mineral Processing Technologies · National Science and Engineering Research Council of Canada

References (35)

Show source-provided references
1. Skin penetration of fatty acids from soap surfactants in cleansers dependent on foam bubble size10.1007/s11743-013-1492-y ↗
2. Neglected food bubbles: The espresso coffee foam10.1007/s11483-011-9220-5 ↗
3. Foams for pharmaceutical and cosmetic application10.1016/j.ijpharm.2010.04.028 ↗
4. Coalescence of dry foam under water injection10.1039/c4sm00476k ↗
5. The significance of froth stability in mineral flotation—A review10.1016/j.cis.2011.03.001 ↗
6. 1999
7. 2013
8. Rheology of adsorbed surfactant monolayers at fluid surfaces10.1146/annurev-fluid-010313-141403 ↗
9. Stability of foam films and surface rheology: An oscillating bubble study at low frequencies10.1021/jp049694e ↗
10. A surface rheological study of non-ionic surfactants at the water-air interface and the stability of the corresponding thin foam films10.1016/j.colsurfa.2006.12.004 ↗
11. Effects of surface forces and film elasticity on foam stability10.1016/j.minpro.2007.08.009 ↗
12. Physical chemistry in foam drainage and coarsening10.1039/b606780h ↗
13. Thermodynamic and mechanical timescales involved in foam film rupture and liquid foam coalescence10.1002/cphc.201402195 ↗
14. A critical review of the growth, drainage and collapse of foams10.1016/j.cis.2015.11.009 ↗
15. Responsive aqueous foams10.1002/cphc.201402580 ↗
16. Smart foams: Switching reversibly between ultrastable and unstable foams10.1002/ange.201102115 ↗
17. Redox-controllable interfacial properties of zwitterionic surfactant featuring selenium atoms10.1021/acs.langmuir.6b02616 ↗
18. PH-responsive nanoemulsions for controlled drug release10.1021/bm4018484 ↗
19. Magnetic surfactants10.1016/j.cocis.2015.08.002 ↗
20. Optical control of surface forces and instabilities in foam films using photosurfactants10.1039/c6sm01846g ↗
21. Responsive foams for nanoparticle delivery10.1016/j.colsurfb.2015.05.038 ↗
22. Effect of temperature on the adsorption of poly(N-isopropylacrylamide) at the air−solution interface10.1021/la981531s ↗
23. Adsorption kinetics of NIPAM-based polymers at the air-water interface as studied by pendant drop and bubble tensiometry10.1021/jp064112+ ↗
24. R.-M. Guillermic, “Propriétés physico-chimiques des mousses: Études approfondies sur des mousses modèles at études exploratoires sur de nouvelles mousses,” PhD thesis, Université Rennes, 2011.
25. UV resonance Raman determination of molecular mechanism of poly(N-isopropylacrylamide) volume phase transition10.1021/jp810685g ↗
26. Shear surface rheology of poly(N-isopropylacrylamide) adsorbed layers at the air-water interface10.1021/ma052552d ↗
27. Dynamics of poly-NIPAM chains in competition with surfactants at liquid interfaces: From thermoresponsive interfacial rheology to foams10.1039/c2sm26666k ↗
28. Coalescence in draining foams10.1021/la026995b ↗
29. The science of foaming10.1016/j.cis.2015.04.001 ↗
30. Generalized view of foam drainage: Experiment and theory10.1021/la9913147 ↗
31. Foaming, foam films, antifoaming and defoaming10.1016/0001-8686(95)00280-4 ↗
32. Coarsening dynamics of three-dimensional levitated foams: From wet to dry
33. Role of surface elasticity in the drainage of soap films10.1103/physrevlett.71.2342 ↗
34. The whole process of phase transition and relaxation of poly(N-isopropylacrylamide) aqueous solution10.1039/c3cp43309a ↗
35. Link between surface elasticity and foam stability10.1039/b822568k ↗