journal article·2014-01-01Open access

Investigation of photoluminescence of Si−O−C(−H) ceramics at an early stage of decarbonization by using high energy excitation

Masaki Narisawa, Taketoshi Kawai, Seiji Watase, Kimihiro Matsukawa, Akihiro Iwase

AIP Advances· Volume 4· Issue 1

Abstract

Si−O−C(−H) ceramics with reduced carbon contents were prepared by pyrolyzing polysiloxane particles in hydrogen at temperatures of 750, 800 and 850 °C. Under HeCd laser irradiation (325 nm), the obtained ceramics show broad spectra peaking at 400–415 nm. On the other hand, the excitation on the higher energy region by an ArF excimer laser (193 nm) induces new PL bands located at short wavelength region of 300 and 355 nm. Such high energy PL bands appear prominently in the ceramics synthesized at 750 °C, and are minor in ceramics synthesized at 800 and 850 °C.
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Research context

OpenAlex topics: Glass properties and applications · Luminescence Properties of Advanced Materials · Silicon Nanostructures and Photoluminescence

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Osaka Prefecture University 1 Graduate School of Engineering, , 1-1 Gakuen-Cho, Naka-Ku, Sakai, Osaka 599-8531, Japan

Osaka Prefecture University 2 Graduate School of Science, , 1-1 Gakuen-Cho, Naka-Ku, Sakai, Osaka 599-8531, Japan

Osaka Municipal Technical Research Institute 3 , 1-6-50, Morinomiya, Joto-ku, Osaka 536-8553, Japan

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