On the solution of the mean-spherical approximation (MSA) for ions in a dipolar solvent in the general case
Source abstract
Abstract
This paper deals with the problem of a mixture of hard spherical ions and central point dipoles, described within the mean-spherical approximation. In this non-primitive model, the species have different diameters (unrestricted case). The first purpose of this work is to establish clear and valid equations for this problem and present a method to solve them. Formulas for the pressure, the internal and Helmholtz energies, and the chemical potentials of the species are given and discussed. The results are illustrated by considering a binary 1–1 electrolyte solution in a water-like dipolar solvent.
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Research context
OpenAlex topics: Chemical and Physical Properties in Aqueous Solutions · Thermodynamic properties of mixtures · Spectroscopy and Quantum Chemical Studies
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Affiliations
Laboratoire PHENIX, CNRS, Sorbonne Université (Campus P.M. Curie) , 4 Place Jussieu, Case 51, F-75005 Paris, France
References (34)
Show source-provided references
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