journal article·2017-10-01Open access

Angle-resolved photoluminescence spectrum of a uniform phosphor layer

Ichiro Fujieda, Masamichi Ohta

AIP Advances· Volume 7· Issue 10

Abstract

A photoluminescence spectrum depends on an emission angle due to self-absorption in a phosphor material. Assuming isotropic initial emission and Lambert-Beer’s law, we have derived simple expressions for the angle-resolved spectra emerging from the top and bottom surfaces of a uniform phosphor layer. The transmittance of an excitation light through the phosphor layer can be regarded as a design parameter. For a strongly-absorbing phosphor layer, the forward flux is less intense and more red-shifted than the backward flux. The red-shift is enhanced as the emission direction deviates away from the plane normal. When we increase the transmittance, the backward flux decreases monotonically. The forward flux peaks at a certain transmittance value. The two fluxes become similar to each other for a weakly-absorbing phosphor layer. We have observed these behaviors in experiment. In a practical application, self-absorption decreases the efficiency of conversion and results in angle-dependent variations in chromaticity coordinates. A patterned phosphor layer with a secondary optical element such as a remote reflector alleviates these problems.
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Research context

OpenAlex topics: Photonic Crystals and Applications · Photonic and Optical Devices · Photochemistry and Electron Transfer Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Electrical and Electronic Engineering, Ritsumeikan University , Kusatsu 525-8577, Japan

Funding

MEXT | Japan Society for the Promotion of Science

References (49)

Show source-provided references
1. Suppressed speckle contrast of blue light emission out of white lamp with phosphors excited by blue laser diodes for high-brightness lighting applications10.1007/s10043-012-0072-0 ↗
2. Incoherentized high-brightness white light generated using blue laser diodes and phosphors -effect of multiple scattering10.2150/jlve.ieij130000499 ↗
3. Laser-driven phosphor-converted white light source for solid-state illumination10.1364/ao.55.001899 ↗
4. Speckle-free phosphor-scattered blue light emitted out of InGaN/GaN laser diode with broadened spectral behavior for high luminance white lamp applications10.1587/transele.e96.c.1391 ↗
5. High power laser-driven ceramic phosphor plate for outstanding efficient white light conversion in application of automotive lighting10.1038/srep31206 ↗
6. Highly efficient laser spotlight illuminator with a novel check-patterned phosphor structure
7. A direct-view laser-phosphor display with a high-reflection wide-angle-scanner
8. Introducing scalable, freeform, immersive, high-definition laser phosphor displays
9. New scheme of a highly-reliable glass-based color wheel for next-generation laser light engine10.1364/ome.7.001029 ↗
10. Improvement of light extraction efficiency of laser-phosphor light source
11. A backlight based on a laser diode and its design considerations
12. Characterization of a liquid crystal/dye cell for a future application in display-integrated photovoltaics10.1117/1.jpe.6.028001 ↗
13. Energy-harvesting laser phosphor display and its design considerations10.1117/1.jpe.7.028001 ↗
14. PFS, K2SiF6:Mn4+: The red-line emitting LED phosphor behind GE’s TriGain technology platform
15. Analysis of wide color gamut of green/red bilayered freestanding phosphor film-capped white LEDs for LCD backlight10.1364/oe.23.00a791 ↗
16. White LEDs using the sharp β-sialon: Eu phosphor and Mn-doped red phosphor for wide-color gamut display applications10.1002/jsid.462 ↗
17. Self-absorption correction for solid-state photoluminescence quantum yields obtained from integrating sphere measurements10.1063/1.2768926 ↗
18. An investigation of self-absorption and corresponding spectral shift in phosphors10.1149/1.3697439 ↗
19. Versatile measuring method of the quantum yield of phosphor systems with high and low photoluminescence
20. 2006 · 150
21. Polarization dependent light extraction of a GaN light emitting diode using dark field angle-resolved photoluminescence spectrometry10.1364/oe.20.017952 ↗
22. Luminescent solar concentrators. 1: Theory of operation and techniques for performance evaluation10.1364/ao.18.003090 ↗
23. Luminescent solar concentrators. 2: Experimental and theoretical analysis of their possible efficiencies10.1364/ao.20.003733 ↗
24. Design, fabrication, and characterization of a luminescent solar concentrator with optimized optical concentration through minimization of optical losses10.1117/1.jpe.6.045504 ↗
25. Large-area luminescent solar concentrators based on ‘stokes-shift-engineered’ nanocrystals in a mass-polymerized PMMA matrix10.1038/nphoton.2014.54 ↗
26. Highly efficient large-area colourless luminescent solar concentrators using heavy-metal-free colloidal quantum dots10.1038/nnano.2015.178 ↗
27. Fabrication and spectroscopic studies on highly luminescent CdSe/CdS nanorod polymer composites10.3762/bjnano.1.11 ↗
28. Luminescent solar concentration with semiconductor nanorods and transfer-printed micro-silicon solar cells10.1021/nn404418h ↗
29. Molecular polarization switching for improved light coupling in luminescent solar concentrators10.1021/jz4013905 ↗
30. Zero-reabsorption doped-nanocrystal luminescent solar concentrators10.1021/nn406360w ↗
31. Energy migration in organic solar concentrators with a molecularly insulated perylene diimide10.1021/acs.jpcc.6b04479 ↗
32. Quantifying self-absorption losses in luminescent solar concentrators10.1364/ao.53.005238 ↗
33. Quality factor of luminescent solar concentrators and practical concentration limits attainable with semiconductor quantum dots10.1021/acsphotonics.6b00307 ↗
34. Simulations of luminescent solar concentrators: Effects of polarization and fluorophore alignment10.1063/1.3467801 ↗
35. Patterned dye structures limit reabsorption in luminescent solar concentrators10.1364/oe.18.00a536 ↗
36. Dye alignment in luminescent solar concentrators: I. Vertical alignment for improved waveguide coupling10.1364/oe.18.000a79 ↗
37. Increased efficiency of luminescent solar concentrators after application of organic wavelength selective mirrors10.1364/oe.20.00a655 ↗
38. Enhanced photon collection in luminescent solar concentrators with distributed Bragg reflectors10.1021/acsphotonics.5b00630 ↗
39. Simple accurate system for measuring absolute photoluminescence quantum efficiency in organic solid-state thin films10.1143/jjap.43.7729 ↗
40. Characterizing the light guiding of fluorescent concentrators10.1063/1.3125524 ↗
41. Spectral-based analysis of thin film luminescent solar concentrators10.1016/j.solener.2010.04.015 ↗
42. 2006 · 350
43. 2005
44. Testing fluorescence lifetime standards using two-photon excitation and time-domain instrumentation: Rhodamine B, coumarin 6 and lucifer yellow10.1007/s10895-014-1368-1 ↗
45. Analysis of the photophysical behavior and rotational-relaxation dynamics of coumarin 6 in nonionic micellar environments: The effect of temperature10.3390/molecules201019343 ↗
46. Dye alignment in luminescent solar concentrators: II. Horizontal alignment for energy harvesting in linear polarizers10.1364/oe.18.000a79 ↗
47. Switchable fluorescent liquid crystals10.1063/1.3250163 ↗
48. Tilted dipole model for bias-dependent photoluminescence pattern10.1063/1.4904064 ↗
49. 2002 · 62