journal article·2024-03-01Open access

Cu-doping induced tuning of magnetic properties and phase transformation in MnBi alloys

Yang Yang, Hui Yu Xu, Shun Da Lu, Zhen Xiang, Lin Feng Chen, Cheng Yu Li, Nguyen Xuan Truong, Wei Lu

AIP Advances· Volume 14· Issue 3

Abstract

This study investigates the effect of Cu doping on the magnetic properties of MnBi alloy at sub-ambient temperatures. The Curie temperatures (Tc) were observed at 175.2 and 161.6 K for Mn52Bi45Cu3 and Mn51Bi45Cu4 alloys, respectively. The Mn55Bi45 sample demonstrates a notable saturation magnetization (Ms) of 72 emu/g, reaching 90% of the theoretical value, indicating the successful synthesis of high-purity ferromagnetic low-temperature phase MnBi. Compared to Mn55Bi45, all Cu-doped samples exhibit higher coercivity (Hc) within the temperature range of 10–200 K. In particular, the sample with 4 at. % Cu exhibits an Hc of 7.4 kOe at 10 K, which is 37 times higher than that of the MnBi sample (0.2 kOe), and it remains significantly higher than that of the 0–3 at. % Cu-doped samples, even at 200 K. Further details of this investigation are presented in this paper.
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Research context

OpenAlex topics: Magnetic Properties of Alloys · Magnetic Properties and Applications · Magnetic properties of thin films

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Shanghai Key Laboratory of D&A for Metal-Functional Materials, School of Materials Science and Engineering, Tongji University 1 , Shanghai 201804, China

Baosteel Magnetics Co. Ltd. 2 , No. 2029, Baoyang Road, Baoshan District, Shanghai 201999, China

Institute of Materials Science, Vietnam Academy of Science and Technology 3 , No. 18, Hoang Quoc Viet Road, Cau Giay District, Hanoi, Vietnam

Vietnam Academy of Science and Technology, The Graduate University of Sciences and Technology 4 , No. 18, Hoang Quoc Viet Road, Cau Giay District, Hanoi, Vietnam

Funding

National Key Research and Development Program of China · China Postdoctoral Science Foundation · Shanghai Municipal Science and Technology

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