journal article·2013-07-01Open access

Gd(III) doping effect on magnetization and water proton relaxivities in ultra small iron oxide nanoparticles

Eun Sook Choi, Wenlong Xu, Myung Ju Baek, Ja Young Park, Joo Hyun Kim, Yongmin Chang, Tae Jeong Kim, Gang Ho Lee

AIP Advances· Volume 3· Issue 7

Abstract

Two samples of ultra small Gd(III) doped iron oxide nanoparticles were prepared to investigate Gd(III) doping effect on longitudinal (r1) and transverse (r2) water proton relaxivities. Gd(III) doping mole percents were 0.2 and 0.4 for samples 1 and 2, respectively. Average particle diameters were 2.5 to 2.1 nm for samples 1 and 2, respectively. Reduced r1 and r2 values were observed in both samples. We attributed this to reduced magnetizations arising from opposing effect of Gd(III) to net magnetizations of Fe(III)/Fe(II) in oxide nanoparticles.
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Research context

OpenAlex topics: Iron oxide chemistry and applications · Magnetic Properties and Synthesis of Ferrites · Characterization and Applications of Magnetic Nanoparticles

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Kyungpook National University 1 Department of Chemistry, College of Natural Sciences, , Taegu 702-701, South Korea

Kyungpook National University 2 Department of Nanoscience and Nanotechnology, , Taegu 702-701, South Korea

Kyungpook National University and Hospital 3 Department of Molecular Medicine and Medical & Biological Engineering, School of Medicine, , Taegu 702-701, South Korea

Kyungpook National University 4 Department of Applied Chemistry, College of Engineering, , Taegu 702-701, South Korea

References (43)

Show source-provided references
1. Chem. Mater. · 1996 · 8 · 177010.1021/cm960077f ↗
2. Aerosol Sci. Technol. · 1993 · 19 · 45310.1080/02786829308959651 ↗
3. Phys. Rev. B · 1998 · 58 · 1416710.1103/PhysRevB.58.14167 ↗
4. Phys. Rev. B · 1992 · 45 · 977810.1103/PhysRevB.45.9778 ↗
5. Chem. Rev. · 1999 · 99 · 229310.1021/cr980440x ↗
6. Chem. Rev. · 1987 · 87 · 90110.1021/cr00081a003 ↗
7. Phys. Chem. Chem. Phys. · 2012 · 14 · 1268710.1039/c2cp41357d ↗
8. Curr. Topic Med. Chem. · 2013 · 13 · 42210.2174/1568026611313040003 ↗
9. Phys. Rev. · 1959 · 116 · 62410.1103/PhysRev.116.624 ↗
10. Phys. Rev. · 1956 · 103 · 57210.1103/PhysRev.103.572 ↗
11. J. Chem. Phys. · 1956 · 24 · 123910.1063/1.1742747 ↗
12. J. Alloy Comp. · 2007 · 427 · 19410.1016/j.jallcom.2006.02.044 ↗
13. J. Magn. Magn. Mater. · 2003 · 257 · 7910.1016/S0304-8853(02)01036-3 ↗
14. Phys. Rev. B · 1990 · 41 · 386610.1103/PhysRevB.41.3866 ↗
15. Rep. Progr. Phys. · 1977 · 40 · 117910.1088/0034-4885/40/10/002 ↗
16. Phys. Rev. B · 1998 · 58 · R591610.1103/PhysRevB.58.R5916 ↗
17. Nanotechnology · 2008 · 19 · 36560310.1088/0957-4484/19/36/365603 ↗
18. ACS Nano · 2009 · 3 · 366310.1021/nn900761s ↗
19. 1978 · 99
20. J. Colloids Interface Sci. · 2005 · 288 · 14010.1016/j.jcis.2005.02.089 ↗
21. Geochim. Cosmochim. Acta · 2001 · 65 · 428910.1016/S0016-7037(01)00696-2 ↗
22. J. Electron Spectro. Relat. Phenomena · 2006 · 150 · 20810.1016/j.elspec.2005.05.006 ↗
23. Phys. Chem. Chem. Phys. · 2006 · 8 · 323210.1039/b518007b ↗
24. 1992 · 4
26. Mater. Lett. · 2008 · 62 · 379310.1016/j.matlet.2008.04.053 ↗
27. J. Solid State Chem. · 2004 · 177 · 376810.1016/j.jssc.2004.07.002 ↗
28. J. Mol. Cat. A: Chem. · 2005 · 232 · 8910.1016/j.molcata.2005.01.022 ↗
29. Chem. Mater. · 2004 · 16 · 362310.1021/cm049345x ↗
30. Crystal Growth Design · 2008 · 8 · 206110.1021/cg800014b ↗
31. Ceram. Int. · 2008 · 34 · 150310.1016/j.ceramint.2007.04.016 ↗
32. J. Mater. Sci. · 1992 · 27 · 101110.1007/BF01197655 ↗
33. Nanotechnology · 2008 · 19 · 08560810.1088/0957-4484/19/8/085608 ↗
34. J. Am. Ceram. Soc. · 2005 · 88 · 331610.1111/j.1551-2916.2005.00598.x ↗
35. J. Phys. D: Appl. Phys. · 2009 · 42 · 11500710.1088/0022-3727/42/11/115007 ↗
36. Solid State Comm. · 1986 · 58 · 11110.1016/0038-1098(86)90865-3 ↗
37. J. Mater. Sci. Lett. · 1992 · 11 · 49610.1007/BF00731116 ↗
38. 1995 · 81
39. 2000 · 125
40. J. Colloid Interface Sci. · 1995 · 171 · 7310.1006/jcis.1995.1152 ↗
41. J. Magn. Magn. Mater. · 2001 · 225 · 1710.1016/S0304-8853(00)01222-1 ↗
42. 1992 · 3
43. J. Chem. Phys. · 1999 · 110 · 540310.1063/1.478435 ↗