A method to fabricate nanoscale gaps in graphene nano-constrictions by electrical breakdown
Source abstract
Abstract
This work reports on a method to open nanoscale gaps in h-shaped graphene nano-constrictions by electrical breakdown at room temperature and pressure below 10−5 mbar. The method was validated on 275 devices, fabricated on eight different chips, using Chemical Vapor Deposition (CVD)-grown graphene from in-house production and from two commercial sources. The gap width was estimated by fitting the I–V traces after electrical breakdown with the Simmons model for the intermediate-voltage range. The statistics on the collected data demonstrates that the method results in normally distributed nanoscale gaps in h-shaped graphene nano-constrictions, with an estimated average width centered around 1 nm and a gap fabrication yield of 95%.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Graphene research and applications · Advancements in Semiconductor Devices and Circuit Design · Semiconductor materials and devices
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Empa, Swiss Federal Laboratories for Materials Science and Technology 1 , Ueberlandstrasse 129, 8600 Duebendorf, Switzerland
Swiss Nanoscience Institute, University of Basel 2 , Basel, Switzerland
Department of Physics, University of Basel 3 , Basel, Switzerland
Funding
H2020 Future and Emerging Technologies · H2020 Marie Sklodowska-Curie Actions
References (24)
Show source-provided references
1. Graphene nanoelectrodes for biomolecular sensing10.1557/jmr.2017.256 ↗
2. Three-terminal graphene single-electron transistor fabricated using feedback-controlled electroburning10.1063/1.4932133 ↗
3. Graphene-contacted ultrashort channel monolayer MoS2 transistors10.1002/adma.201702522 ↗
4. Graphene nanogap electrodes in electrical biosensing10.1016/j.bios.2018.11.049 ↗
5. Atomically thin p–n junctions with van der Waals heterointerfaces10.1038/nnano.2014.150 ↗
6. Robust graphene-based molecular devices10.1038/s41565-019-0533-8 ↗
7. Optimized graphene electrodes for contacting graphene nanoribbons10.1016/j.carbon.2021.08.001 ↗
8. Building high-throughput molecular junctions using indented graphene point contacts10.1002/ange.201205607 ↗
9. Precise milling of nano-gap chains in graphene with a focused helium ion beam10.1088/0957-4484/27/32/325302 ↗
10. Atomic-scale electron-beam sculpting of near-defect-free graphene nanostructures10.1021/nl200369r ↗
11. High-yield fabrication of nm-size gaps in monolayer CVD graphene10.1039/c4nr01838a ↗
12. Nanoscale control of graphene electrodes10.1039/c4cp03257h ↗
13. Room-temperature gating of molecular junctions using few-layer graphene nanogap electrodes10.1021/nl202065x ↗
14. Direct writing of electronic devices on graphene oxide by catalytic scanning probe lithography10.1038/ncomms2200 ↗
15. Graphene at high bias: Cracking, layer by layer sublimation, and fusing10.1021/nl204236u ↗
16. Contacting strategies for molecular electronics
17. From electroburning to sublimation: Substrate and environmental effects in the electrical breakdown process of monolayer graphene10.1039/c7nr05348g ↗
18. Current-induced cleaning of graphene10.1063/1.2789673 ↗
19. Generalized formula for the electric tunnel effect between similar electrodes separated by a thin insulating film10.1063/1.1702682 ↗
20. Comment: [L8D2Q2M0]Generalized formula for the electric tunnel effect between similar electrodes separated by a thin insulating film[R8D2Q2M1] [J. Appl. Phys. 34, 1793 (1963)]10.1063/1.5019788 ↗
21. See https://docs.scipy.org/doc/scipy/reference/generated/scipy.optimize.least_squares.html (last access December 29, 2021.
22. Work function engineering of graphene10.3390/nano4020267 ↗
23. Tuning the graphene work function by electric field effect10.1021/nl901572a ↗
24. Characteristic work function variations of graphene line defects10.1021/acsami.6b04853 ↗