journal article·2018-04-01Open access

Modification of YNbO4 and YNbTiO6 photoluminescence by nitrogen doping

H. Pei, L. M. Su, G. M. Cai, Z. P. Jin

AIP Advances· Volume 8· Issue 4

Abstract

Niobates as multifunctional materials were of vital importance in the industry production and daily life. In present work, niobates YNbO4 and YNbTiO6 are investigated as luminescence materials. The compounds have self-activated luminescence, and it is discussed how nitrogen doping affects their electronic structure and optical properties. Various analytical techniques, including x-ray diffraction, nitrogen-content analysis, x-ray photoelectron spectroscopy, scanning electron microscopy, UV-vis absorption spectroscopy and vacuum ultraviolet emission spectroscopy at variable temperature, were used to characterize the structure, composition, crystallinity and optical performance of these niobates. By considering the luminescence mechanisms in YNbO4 and YNbTiO6, the enhanced luminescence obtained upon nitrogen doping is attributed to the presence of oxygen vacancies and nitrogen levels, which changes the band gaps of the materials. Present work demonstrates the use of nitrogen doping for improving the photoluminescence properties of self-activated niobates.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Microwave Dielectric Ceramics Synthesis · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Materials Science and Engineering, Central South University , Changsha, Hunan 410083, P. R. China

Funding

Hunan Province & Technology Department · The Project of Innovation-Driven Plan in Central South University · National Natural Science Foundation of China

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