journal article·2022-09-01Open access

The melt-back etching effect of the residual Ga in the reactor for GaN grown on (111) Si

Zhenzhuo Zhang, Jing Yang, Degang Zhao, Baibin Wang, Yuheng Zhang, Feng Liang, Ping Chen, Zongshun Liu, Yuhao Ben

AIP Advances· Volume 12· Issue 9

Abstract

The reaction between gallium (Ga) and silicon (Si), termed melt-back etching, greatly deteriorates the quality of GaN grown on a Si substrate. In this paper, the mechanism of melt-back etching was investigated layer-by-layer in a GaN/AlN/Si system. It is found that the environment of the reactor plays a critical role in melt-back etching, which may happen as early as during the baking process. Drawing on experimental evidence and analyses, a two-step melt-back etching model is proposed. Finally, optimized pretreatments including an AlN precoating process and reduction in baking temperature were used to successfully solve the etching problem and verify the model.
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Research context

OpenAlex topics: GaN-based semiconductor devices and materials · Semiconductor materials and devices · Thin-Film Transistor Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Integrated Optoelectronics, Institute of Semiconductor, Chinese Academy of Science 1 , Beijing 100083, China

College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences 2 , Beijing 100049, China

Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences 3 , Beijing 100049, China

Funding

National Key Research and Development Program of China · National Natural Science Foundation of China · Strategic Priority Research Program of Chinese Academy of Sciences · Youth Innovation Promotion Association · Beijing Nova Program · Young Elite Scientists Sponsorship Program by CAST

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