journal article·2011-09-01Open access

Room temperature ferromagnetism in ZnO prepared by microemulsion

Qingyu Xu, Zheng Wen, Hua Zhang, Xiaosi Qi, Wei Zhong, Liguo Xu, Di Wu, Kai Shen, Mingxiang Xu

AIP Advances· Volume 1· Issue 3

Abstract

Clear room temperature ferromagnetism has been observed in ZnO powders prepared by microemulsion. The O vacancy (VO) clusters mediated by the VO with one electron (F center) contributed to the ferromagnetism, while the isolated F centers contributed to the low temperature paramagnetism. Annealing in H2 incorporated interstitial H (Hi) in ZnO, and removed the isolated F centers, leading to the suppression of the paramagnetism. The ferromagnetism has been considered to originate from the VO clusters mediated by the Hi, leading to the enhancement of the coercivity. The ferromagnetism disappeared after annealing in air due to the reduction of Hi.
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Research context

OpenAlex topics: ZnO doping and properties · Copper-based nanomaterials and applications · Ga2O3 and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Southeast University 1 Department of Physics, , Nanjing 211189, China

Nanjing University 2 Department of Materials Science and Engineering, , Nanjing 210008, China

Nanjing University 3 Department of Physics, , Nanjing 210008, China

Nanjing University of aeronautics and Astronautics 4 School of Materials Science and Technology, , Nanjing 210016, China

Funding

National Natural Science Foundation of China

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