Electrochemical kinetics and dimensional considerations, at the nanoscale
Source abstract
Abstract
It is shown that the consideration of the density of states variation in nanoscale electrochemical systems yields modulations in the rate constant and concomitant electrical currents. The proposed models extend the utility of Marcus-Hush-Chidsey (MHC) kinetics to a larger class of materials and could be used as a test of dimensional character. The implications of the study are of much significance to an understanding and modulation of charge transfer nanostructured electrodes.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Electrochemical Analysis and Applications · Conducting polymers and applications · Molecular Junctions and Nanostructures
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
University of California 1 Department of Electrical Engineering, , San Diego, La Jolla, CA, 92093, USA
University of California 2 Program in Materials Science, Department of Mechanical Engineering, , San Diego, La Jolla, CA, 92093, USA
Funding
National Science Foundation · Defense Advanced Research Projects Agency
References (27)
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