journal article·2013-03-01Open access

Resistive switching characteristics of Pt/TaOx/HfNx structure and its performance improvement

Qigang Zhou, Jiwei Zhai

AIP Advances· Volume 3· Issue 3

Abstract

The refractory transition metal nitride (TMN) film Hafnium nitride (HfNx) was successfully prepared on silicon-based substrates as bottom electrodes for resistive random access memory (RRAM) cells in Pt (top)/metal oxide/ HfNx (bottom) sandwich structure. The reproducible resistive switching (RS) characteristics of the memory cells were studied systematically for RRAM applications. The advantages of adopting HfNx instead of Pt as bottom electrode material were demonstrated, including the improvement of the low resistive state value, the RS endurance and the uniformity of RS parameters. The composition and chemical bonding states of the prepared HfNx was analyzed by X-ray photoelectron spectroscopy (XPS) technique. The nitrogen content in the HfNx and the Gibbs free energy of the corresponding metal oxide formation has great influences on the RS properties. The oxygen reservoir ability and diffusion barrier effect of the HfNx play a key role in the RS performance improvement of the RRAM devices.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advanced Memory and Neural Computing · Ferroelectric and Negative Capacitance Devices · Transition Metal Oxide Nanomaterials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Tongji University 1 Functional Materials Research Laboratory, , Shanghai 200092, China

Leshan Normal University 2 School of Physics and Electronic Engineering, , Leshan 614000, China

References (40)

Show source-provided references
1. A fast, high-endurance and scalable non-volatile memory device made from asymmetric Ta2O5−x/TaO2−x bilayer structures10.1038/nmat3070 ↗
2. Nanoscale resistive switching in SrTiO3 thin films10.1002/pssr.200701003 ↗
3. Redox-Based Resistive Switching Memories - Nanoionic Mechanisms10.1002/adma.200900375 ↗
4. Separation of bulk and interface contributions to electroforming and resistive switching behavior of epitaxial Fe-doped SrTiO310.1063/1.3100209 ↗
5. Exponential ionic drift: Fast switching and low volatility of thin-film memristors10.1007/s00339-008-4975-3 ↗
6. Improved endurance of resistive switching TiO2 thin film by hourglass shaped Magneéli filaments10.1063/1.3600784 ↗
7. Effect of ZrOx/HfOx bilayer structure on switching uniformity and reliability in nonvolatile memory applications10.1063/1.3491803 ↗
8. Al electrode dependent transition to bipolar resistive switching characteristics in pure TiO2 films10.1063/1.3032896 ↗
9. Improved resistive switching properties in Ti/TiOx/La0.7Ca0.3MnO3/Pt stacked structures10.1016/j.ssc.2009.09.032 ↗
10. Low power and high speed bipolar switching with a thin reactive Ti buffer layer in robust HfO2 based RRAM
11. Bipolar resistive switching memory using bilayer TaOx/WOx films10.1016/j.sse.2012.05.028 ↗
12. Highly uniform and reliable resistance switching properties in bilayer WOx/NbOx RRAM devices10.1002/pssa.201127659 ↗
13. High-speed and localized resistive switching characteristics of double-layer SrZrO3 memory devices10.1088/0022-3727/43/29/295404 ↗
14. Effects of Ti top electrode thickness on the resistive switching behaviors of rf-sputtered ZrO2 memory films10.1063/1.3231872 ↗
15. Dependence of crystal structure and work function of WNx films on the nitrogen content10.1063/1.2349313 ↗
16. Influence of process parameters on properties of reactively sputtered tungsten nitride thin films10.1116/1.3698399 ↗
17. Physical and electrical characteristics of HfN gate electrode for advanced MOS devices10.1109/LED.2003.812143 ↗
18. Investigation of Molybdenum Nitride Gate on SiO2 and HfO2 for MOSFET Application10.1149/1.2158576 ↗
19. Superconducting and normal-state properties of vanadium nitride10.1103/PhysRevB.29.6198 ↗
20. Oxidation of vanadium nitride and titanium nitride coatings10.1016/j.susc.2006.12.010 ↗
21. Low-resistivity ZrNx metal gate in MOS devices10.1016/j.sse.2005.06.021 ↗
22. Preparation and characterization of CrNxOy thin films: The effect of composition and structural features on the electrical behavior
23. Role of TaON interface for CuxO resistive switching memory based on a combined model10.1063/1.3078824 ↗
24. Roles of interfacial TiOxN1-x layer and TiN electrode on bipolar resistive switching in TiN/TiO2/TiN frameworks
25. Local oxidation of metal and metal nitride films10.1116/1.1723269 ↗
26. Comparison of TiN, ZrN and CrN hard nitride coatings: Electrochemical and thermal oxidation10.1016/S0040-6090(97)00069-2 ↗
27. Thermal Oxidation of Reactively Sputtered Titanium Nitride and Hafnium Nitride Films10.1149/1.2119919 ↗
28. Structural, optical, and electrical properties of WOxNy films deposited by reactive dual magnetron sputtering10.1016/j.surfcoat.2006.06.008 ↗
29. Thermally robust HfN metal as a promising gate electrode for advanced MOS device applications, Electron Devices10.1109/TED.2004.825110 ↗
30. In situ Formation of HfN/HfSiON Gate Stacks with 0.5 nm Equivalent Oxide Thickness Utilizing Electron Cyclotron Resonance Plasma Sputtering on Three-Dimensional Si Structures10.1143/JJAP.50.04DA09 ↗
31. Highly Uniform Switching of Tantalum Embedded Amorphous Oxide Using Self-Compliance Bipolar Resistive Switching10.1109/LED.2010.2101044 ↗
32. Bipolar switching behavior in TiN/ZnO/Pt resistive nonvolatile memory with fast switching and long retention10.1088/0268-1242/23/7/075019 ↗
33. Forming-free resistive switching behavior in Nd2O3, Dy2O3, and Er2O3 films fabricated in full room temperature10.1063/1.3638490 ↗
34. Switching the electrical resistance of individual dislocations in single-crystalline SrTiO310.1038/nmat1614 ↗
35. Unipolar resistive switching characteristics of pnictogen oxide films: Case study of Sb2O510.1063/1.4766415 ↗
36. Effects of Postdeposition Annealing on the Characteristics of HfOxNy Dielectrics on Germanium and Silicon Substrates10.1149/1.2203097 ↗
37. Improved endurance behavior of resistive switching in (Ba,Sr)TiO3 thin films with W top electrode10.1063/1.3039809 ↗
38. Characterization of Hafnium-Zirconium-Oxide-Nitride films grown by ion beam assisted deposition10.1016/j.vacuum.2011.10.001 ↗
39. Endurance improvement of resistance switching behaviors in the La0.7Ca0.3MnO3 film based devices with Ag–Al alloy top electrodes10.1063/1.3309473 ↗
40. Resistance-switching properties of La0.67Ca0.33MnO3 thin films with Ag–Al alloy top electrodes10.1007/s00339-009-5333-9 ↗