Miniaturizing gas sensors combining mid-infrared interband cascade light emitting diodes with substrate-integrated hollow waveguides
Source abstract
Abstract
In this study, we report a compact and versatile gas sensor system combining mid-infrared interband cascade light emitting diodes (MIR-ICLEDs) with substrate-integrated hollow waveguides (iHWGs) toward miniaturized gas sensors. Two readily exchangeable MIR-ICLEDs with center emission wavelengths of 3.4 µm (2941 cm−1) and 5.7 µm (1754 cm−1), respectively, were integrated into a modular sensor system using the iHWG simultaneously as a miniaturized gas cell. The performance of the sensor system for quantitative analysis was evaluated based on calibration functions established for four analytes (i.e., methane, isobutane, acetone, and acetaldehyde) within the respective spectral regions. The utility of such a sensor system as a non-dispersive infrared sensor was tested for various scenarios, including the application of spectral filters, the performance of the individual ICLEDs, and in the analysis of gas mixtures. Furthermore, we demonstrated that the modularity of the sensor design facilitates flexible adaptation to target gas species and available sample volumes, differentiating individual components within gas mixtures.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Spectroscopy and Laser Applications · Gas Sensing Nanomaterials and Sensors · Photonic and Optical Devices
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute of Analytical and Bioanalytical Chemistry, Ulm University 1 , Albert-Einstein-Allee 11, D-89081 Ulm, Germany
Nanoplus Advanced Photonics Gerbrunn GmbH 2 , Oberer Kirschberg 4, 97218 Gerbrunn, Germany
Laser Components Germany GmbH 3 , Werner-von-Siemens-Strasse 15, D-82140 Olching, Germany
Hahn-Schickard 4 , Sedanstrasse 14, D-89077 Ulm, Germany
Funding
Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg · Horizon 2020 Framework Program · SFI Digital Food Quality
References (53)
Show source-provided references
1. Spectroscopic sensors for in-line bioprocess monitoring in research and pharmaceutical industrial application10.1007/s00216-016-0068-x ↗
2. Detection of volatile organic compounds: From chemical gas sensors to terahertz spectroscopy10.1515/revac-2021-0127 ↗
3. Application of near and mid-infrared spectroscopy to determine cheese quality and authenticity10.1007/s11947-007-0033-y ↗
4. Emerging trends in optical sensing of glycemic markers for diabetes monitoring10.1016/j.trac.2014.09.005 ↗
5. A review of methane gas detection sensors: Recent developments and future perspectives10.3390/inventions5030028 ↗
6. Gas leakage detection and smart alerting and prediction using IoT
7. A wireless gas sensor network to monitor indoor environmental quality in schools10.3390/s18124345 ↗
8. A survey of wireless sensor network based air pollution monitoring systems10.3390/s151229859 ↗
9. Sick building syndrome—A case study in a multistory centrally air-conditioned building in the Delhi city10.1016/j.buildenv.2006.10.013 ↗
10. World Health Organization · 2024
11. Sensing technologies for detection of acetone in human breath for diabetes diagnosis and monitoring10.3390/diagnostics8010012 ↗
12. Clinical study of multiple breath biomarkers of asthma and COPD (NO, CO2, CO and N2O) by infrared laser spectroscopy10.1088/1752-7155/5/3/037108 ↗
13. Infrared cavity ring-down spectroscopy for detecting non-small cell lung cancer in exhaled breath10.1088/1752-7163/ac5e4f ↗
14. The HITRAN2016 molecular spectroscopic database10.1016/j.jqsrt.2017.06.038 ↗
15. Cavity ring-down spectroscopy: Experimental schemes and applications10.1080/014423500750040627 ↗
16. Trace gas monitoring with infrared laser-based detection schemes10.1007/s00340-007-2875-4 ↗
17. Photoacoustic techniques for trace gas sensing based on semiconductor laser sources10.3390/s91209616 ↗
18. Infrared laser based on intersubband transitions in quantum wells10.1006/spmi.1995.1017 ↗
19. Quantum cascade laser10.1126/science.264.5158.553 ↗
20. Next-generation mid-infrared sources10.1088/2040-8986/aa939b ↗
21. The interband cascade laser10.3390/photonics7030075 ↗
22. Mid-infrared quantum cascade lasers10.1038/nphoton.2012.143 ↗
23. Quantum cascade lasers for mid-infrared spectroscopy10.1016/s0924-2031(02)00038-3 ↗
24. Trace sensing with miniaturized mid-infrared sensors
25. Breath analysis with broadly tunable quantum cascade lasers10.1021/ac3030703 ↗
26. Non-dispersive infrared gas sensing technology: A review10.1109/jsen.2021.3130034 ↗
27. Advanced mid-infrared lightsources above and beyond lasers and their analytical utility10.1007/s44211-022-00133-3 ↗
28. LED-based NDIR natural gas analyzer10.1088/1757-899x/108/1/012036 ↗
29. Filter-free nondispersive infrared sensing using narrow-bandwidth mid-infrared thermal emitters10.7567/apex.7.012103 ↗
30. Plasmonic thermal emitters for dynamically tunable infrared radiation10.1002/adom.201600993 ↗
31. A low cost MEMS based NDIR system for the monitoring of carbon dioxide in breath analysis at ppm levels10.1016/j.snb.2016.04.016 ↗
32. Mid-infrared light-emitting diodes10.1016/B978-0-08-102709-7.00002-4 ↗
33. Improved mid-infrared interband cascade light-emitting devices10.1117/1.oe.57.1.011002 ↗
34. Effects of ion bombardment on interband cascade laser structures10.1117/12.2545898 ↗
35. Mid-infrared interband cascade light emitting devices grown on off-axis silicon substrates10.1364/oe.435825 ↗
36. High-power MWIR cascaded InAs–GaSb superlattice LEDs10.1109/jqe.2009.2013176 ↗
37. Increase in midwave infrared light emitting diode light output due to substrate thinning and texturing10.1063/1.2430484 ↗
38. Waveguide-enhanced mid-infrared chem/bio sensors10.1039/c3cs60173k ↗
39. Towards the determination of isoprene in human breath using substrate-integrated hollow waveguide mid-infrared sensors10.1088/1752-7155/8/2/026003 ↗
40. A hyphenated preconcentrator-infrared-hollow-waveguide sensor system for N2O sensing10.1038/s41598-018-23961-8 ↗
41. Hollow-waveguide gas sensing with room-temperature quantum cascade lasers10.1049/ip-opt:20030673 ↗
42. Optimized design of substrate-integrated hollow waveguides for mid-infrared gas analyzers10.1088/2040-8978/16/9/094006 ↗
43. polyHWG: 3D printed substrate-integrated hollow waveguides for mid-infrared gas sensing10.1021/acssensors.7b00649 ↗
44. iHWG-ICL: Methane sensing with substrate-integrated hollow waveguides directly coupled to interband cascade lasers10.1021/acssensors.6b00238 ↗
45. Towards miniaturized gas sensors based on substrate-integrated hollow waveguides and interband cascade light emitting diodes10.1039/d2sd00220e ↗
46. High efficiency mid-infrared interband cascade LEDs grown on low absorbing substrates emitting >5 mW of output power10.1117/1.oe.58.11.117106 ↗
47. Vibrational spectroscopy of C H bonds of methane and tetramethylsilane in liquid argon solutions10.1016/0009-2614(93)87008-q ↗
48. Calculation of the frequencies and intensities in the infrared spectra of matrix-isolated tert-butyl radical and isobutane10.1021/j150662a043 ↗
49. Quantitative measurements of broad-band mid-infrared absorption spectra of formaldehyde, acetaldehyde, and acetone at combustion-relevant temperatures near 5.7 µm10.1016/j.jqsrt.2020.106981 ↗
50. Substrate-integrated hollow waveguides: A new level of integration in mid-infrared gas sensing10.1021/ac402391m ↗
51. Miniature low-cost carbon dioxide sensor for mobile devices10.1109/jsen.2017.2682638 ↗
52. Compact mid-infrared gas sensing enabled by an all-metamaterial design10.1021/acs.nanolett.0c00483 ↗
53. Smart mid-infrared metasurface microspectrometer gas sensing system10.1038/s41378-024-00697-2 ↗