journal article·2019-06-01Open access

A rapid and green method for the removal of anionic dyes from aqueous solution using sulfobetaine-modified magnetic nanoparticles

Jie Qiao, Shan Gao, Jiao Yao, Liting Zhang, Ningbo Li

AIP Advances· Volume 9· Issue 6

Abstract

A novel and green adsorbent based on sulfobetaine-modified magnetic Fe3O4 nanoparticles (SBMNPs) was successfully synthesized via a convenient one-step chemical coprecipitation method and applied to the removal of the anionic dyes methyl blue (MB) and amaranth (AM) from aqueous solution. The morphology and properties of the SBMNPs were characterized using various methods, including Fourier-transform infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy, and vibrating-sample magnetometry. The obtained SBMNPs were easily dispersible in water and exhibited excellent superparamagnetic behavior. For the adsorption process, four experimental parameters, namely, the solution pH, initial dye concentration, reaction time, and adsorbent dosage, were optimized. The adsorption process was remarkably fast and reached equilibrium within 15 min. The isotherm data were consistent with the Langmuir model, and the maximum adsorption capacities of the SBMNPs were 127.06 mg·g−1 and 57.01 mg·g−1 for MB and AM, respectively, which exceed those reported for other adsorbents. The adsorption kinetics were well fitted by a pseudo-second-order model, which indicated chemical adsorption. Furthermore, the SBMNPs displayed good recyclability, removing 80.92% of MB and 77.49% of AM in the fifth cycle. Owing to their rapid adsorption properties and facile synthesis from green and inexpensive starting materials, the SBMNPs may represent a promising new adsorbent for the removal of anionic dyes from aqueous solution.
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Research context

OpenAlex topics: Adsorption and biosorption for pollutant removal · Nanomaterials for catalytic reactions · Graphene and Nanomaterials Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Basic Medicine, Shanxi Medical University , Taiyuan 030001, P. R. China

Funding

PhD Start-Up Foundation of shanxi medical university · the 331 early career researcher grant of shanxi medical university · the key research and decelopment projects of shanxi province · National Natural Science Foundation of China · Shanxi Province Science Foundation for Youths

References (42)

Show source-provided references
1. Adsorption of rhodamine B and methylene blue dyes using waste of seeds of Aleurites Moluccana, a low cost adsorbent10.1016/j.aej.2016.03.017 ↗
2. Polyacrylamide-phytic acid-polydopamine conducting porous hydrogel for efficient removal of water-soluble dyes10.1038/s41598-017-08220-6 ↗
3. Sunlight assisted degradation of dye molecules and reduction of toxic Cr(VI) in aqueous medium using magnetically recoverable Fe3O4/reduced graphene oxide nanocomposite10.1039/c5ra25035h ↗
4. Degradation and detoxification of synthetic dyes and textile industry effluents by newly isolated Leptosphaerulina sp from Colombia10.1186/s40643-016-0084-x ↗
5. Modification of activated carbon via grafting polyethyleneimine to remove amaranth from water10.1007/s13201-017-0557-x ↗
6. Synthesis of zeolite a from metakaolin and its application in the adsorption of cationic dyes10.3390/app8040608 ↗
7. Development of chitosan/bentonite hybrid composite to remove hazardous anionic and cationic dyes from colored effluent10.1016/j.jece.2016.07.004 ↗
8. Experimental and molecular dynamics simulation study of specific ion effect on the graphene oxide surface and investigation of the influence on reactive extraction of model dye molecule at water-organic interface10.1021/acs.jpcc.6b02787 ↗
9. Synthesis of Zn/Al layered double hydroxides as adsorbent for congo red and direct violet removal from aqueous solution10.1063/1.5065003 ↗
10. Removal of textile dyes and metallic ions using polyelectrolytes and macroelectrolytes containing sulfonic acid groups10.1016/j.jenvman.2016.04.004 ↗
11. Adsorption of dyes using different types of clay: A review10.1007/s13201-015-0322-y ↗
12. Effect of structure and chemical activation on the adsorption properties of green clay minerals for the removal of cationic dye10.3390/app8112302 ↗
13. Understanding the factors affecting the adsorption of lanthanum using different adsorbents: A critical review10.1016/j.chemosphere.2018.04.053 ↗
14. Removal of dye molecules from aqueous solution by carbon nanotubes and carbon nanotube functional groups: Critical review10.1039/c7ra09377b ↗
15. A rapid method for the removal of methyl blue dye from wastewater by magnetic nanoparticles Mn-ferrites10.1080/19443994.2014.902331 ↗
16. Controlled synthesis and magnetic properties of bimagnetic spinel ferrite CoFe2O4 and MnFe2O4 nanocrystals with core-shell architecture10.1021/ja302856z ↗
17. Structural and magnetic properties of CoFe2O4/NiFe2O4 core/shell nanocomposite prepared by the hydrothermal method10.1016/j.jmmm.2015.07.039 ↗
18. Dehydrogenation mechanism of ball-milled MgH2 doped with ferrites (CoFe2O4, ZnFe2O4, MnFe2O4 and Mn0.5Zn0.5Fe2O4) nanoparticles10.1016/j.jallcom.2015.04.135 ↗
19. Simultaneous extraction, enrichment and removal of dyes from aqueous solutions using a magnetic aqueous micellar two-phase system10.3390/app7121257 ↗
20. Cigarette soot activated carbon modified with Fe3O4 nanoparticles as an effective adsorbent for As(III) and As(V): Material preparation, characterization and adsorption mechanism study10.1016/j.molliq.2017.08.055 ↗
21. Bentonite coated with magnetite Fe3O4 nanoparticles as a novel adsorbent for copper (II) ions removal from water/wastewater10.1016/j.eti.2018.02.005 ↗
22. Preparation and characterization of CNSR functionalized Fe3O4 magnetic nanoparticles: An efficient adsorbent for the removal of cadmium ion from water10.1016/j.jece.2017.08.036 ↗
23. Graphene–Fe3O4 nanohybrids: Synthesis and excellent electromagnetic absorption properties10.1063/1.4774243 ↗
24. A highly sensitive magnetic biosensor for detection and quantification of anticancer drugs tagged to superparamagnetic nanoparticles10.1063/1.4862395 ↗
25. Surface modified magnetic nanoparticles as efficient and green sorbents: Synthesis, characterization, and application for the removal of anionic dye10.1016/j.jmmm.2015.06.024 ↗
26. Fast removal and recovery of amaranth by modified iron oxide magnetic nanoparticles10.1016/j.chemosphere.2009.02.065 ↗
27. A novel-green adsorbent based on betaine-modified magnetic nanoparticles for removal of methyl blue10.1016/j.scib.2017.01.038 ↗
28. Sulfobetaine (dimethylsulfoniopropionate) and glycine betaine show incompatible involvement in crucial Ehrlich ascites carcinoma in mice
29. Application of Mn/MCM-41 as an adsorbent to remove methyl blue from aqueous solution10.1016/j.jcis.2014.05.004 ↗
30. Fe3O4 nanoparticles as an efficient and magnetically recoverable catalyst for Friedel-Crafts acylation reaction in solvent-free conditions10.1080/00397911.2012.663048 ↗
31. Hyperthermia treatment of tumors by mesenchymal stem cell-delivered superparamagnetic iron oxide nanoparticles10.2147/ijn.s94255 ↗
32. A magnetic nanomaterial modified with poly-lysine for efficient removal of anionic dyes from water10.1016/j.cej.2014.09.094 ↗
33. Ultra-large-scale syntheses of monodisperse nanocrystals10.1038/nmat1251 ↗
34. A dual function magnetic nanomaterial modified with lysine for removal of organic dyes from water solution10.1016/j.cej.2013.11.022 ↗
35. Efficient removal of organic dyes from aqueous solution with ecofriendly biomass-derived carbon@montmorillonite nanocomposites by one-step hydrothermal process10.1016/j.cej.2013.03.015 ↗
36. Surface modified magnetic nanoparticles as efficient and green sorbents: Synthesis, characterization, and application for the removal of anionic dye10.1016/j.jmmm.2015.06.024 ↗
37. Removal of heavy metal ions from aqueous solution using Fe3O4-SiO2-poly(1,2-diaminobenzene) core-shell sub-micron particles10.1016/j.jcis.2012.07.066 ↗
38. Performances of methyl blue and arsenic(V) adsorption from aqueous solution onto magnetic 0.8Ni0.5Zn0.5Fe2O4/0.2SiO2 nanocomposites10.1007/s11270-014-1973-2 ↗
39. Selective adsorption of amaranth dye on Fe3O4/MgO nanoparticles10.1016/j.molliq.2016.03.084 ↗
40. Magnetic field assisted adsorption of methyl blue onto organo-bentonite10.1016/j.clay.2011.11.019 ↗
41. Adsorption characteristics of methyl blue onto magnetic Ni0.5Zn0.5Fe2O4 nanoparticles prepared by the rapid combustion process10.1007/s11051-013-1679-1 ↗
42. Efficient removal of dyes from aqueous solution by mesoporous nanocomposite Al2O3/Ni0.5Zn0.5Fe2O4 microfibers10.1007/s11270-013-1819-3 ↗