journal article·2017-08-01Open access

Improved efficiency of organic solar cells using Au NPs incorporated into PEDOT:PSS buffer layer

Francis Otieno, Ndivhuwo P. Shumbula, Mildred Airo, Mlambo Mbuso, Nosipho Moloto, Rudolph M. Erasmus, Alexander Quandt, Daniel Wamwangi

AIP Advances· Volume 7· Issue 8

Abstract

Au based plasmonic phenomenon inside the hole transport layer poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) of an organic solar cell based on blend of poly(3-hexylthiophene) (P3HT) and [6:6]-phenyl-C61-butyric acid (PCBM) is investigated. The concentration of the Au nanoparticles synthesized by wet chemical reduction is one of the key factors to strong light trapping when the spherical gold nanoparticles are blended into the PEDOT:PSS solution. Studies of the influence of the concentration of nanoparticles distribution in the PEDOT:PSS were carried out using UV–Vis spectroscopy and atomic force microscopy. Electrical characteristics of the pristine device and of device with metallic nanostructures were analyzed from J –V characteristics to observe the plasmonic effects on the performance in the P3HT:PCBM organic solar cells. The origin of the photocurrent enhancements with varying Au nanoparticles concentrations on PEDOT:PSS are discussed.
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Quantum Dots Synthesis And Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Material Physics Research Institute, School of Physics, University of the Witwatersrand 1 , Private Bag 3, Wits 2050, Johannesburg, South Africa

Materials for Energy Research group, University of the Witwatersrand 3 , Private Bag 3, 2050 Wits, Johannesburg, South Africa

Museo Storico della Fisica e Centro Studi e Ricerche Enrico Fermi 5 , Piazza del Viminale 1, 00184 Roma, Italy

School of Chemistry, University of the Witwatersrand 2 , Private Bag 3, Wits 2050, Republic of South Africa

Department of Physics, University of Pretoria 4 , Pretoria 0002, South Africa

Funding

Material Energy Research Group · South Africa - Itally bilateral project on plasmonics for a better efficiency of solar cells · University of Witwatersrand · National Research Foundation

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