journal article·2016-02-01Open access

Enhanced Pr3+ photoluminescence by energy transfer in SrF2 : Eu2+, Pr3+ phosphor

M. Y. A. Yagoub, H. C. Swart, P. Bergman, E. Coetsee

AIP Advances· Volume 6· Issue 2

Abstract

Efficient energy transfer was demonstrated in the SrF2 : Eu2+, Pr3+ phosphor synthesized by the co-precipitation method. Results obtained with X-ray diffraction (XRD), scanning electron microscopy (SEM), x-ray spectroscopy (XPS), photoluminescence (PL) and decay curves proposed the UV-Vis energy transfer process. The energy transfer process between the Eu2+ and Pr3+ ions in SrF2 was investigated to evaluate the potential of the Eu2+ ion as a sensitizer for the Pr3+ ion. The results proposed that Eu2+ could be a good sensitizer for absorbing the UV photons and efficiently enhancing the Pr3+ emission intensity. The energy transfer process was effective until concentration quenching for the Pr3+ ions occurred. The concentration quenching was attributed to cross-relaxation between the Pr3+ ions.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Radiation Detection and Scintillator Technologies · Gas Sensing Nanomaterials and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

University of the Free State 1 Department of Physics, , PO Box 339, Bloemfontein, ZA9300, South Africa

Linköping University 2 Department of Physics, Chemistry and Biology, , Linköping, Sweden

Funding

South African Research Foundation

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