journal article·2016-03-01Open access

Material/element-dependent fluorescence-yield modes on soft X-ray absorption spectroscopy of cathode materials for Li-ion batteries

Daisuke Asakura, Eiji Hosono, Yusuke Nanba, Haoshen Zhou, Jun Okabayashi, Chunmei Ban, Per-Anders Glans, Jinghua Guo, Takashi Mizokawa, Gang Chen, Andrew J. Achkar, David G. Hawthron, Thomas Z. Regier, Hiroki Wadati

AIP Advances· Volume 6· Issue 3

Abstract

We evaluate the utilities of fluorescence-yield (FY) modes in soft X-ray absorption spectroscopy (XAS) of several cathode materials for Li-ion batteries. In the case of total-FY (TFY) XAS for LiNi0.5Mn1.5O4, the line shape of the Mn L3-edge XAS was largely distorted by the self-absorption and saturation effects, while the distortions were less pronounced at the Ni L3 edge. The distortions were suppressed for the inverse-partial-FY (IPFY) spectra. We found that, in the cathode materials, the IPFY XAS is highly effective for the Cr, Mn, and Fe L edges and the TFY and PFY modes are useful enough for the Ni L edge which is far from the O K edge.
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Research context

OpenAlex topics: X-ray Spectroscopy and Fluorescence Analysis · Electron and X-Ray Spectroscopy Techniques · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Institute of Advanced Industrial Science and Technology 1 Energy Technology Research Institute, , Tsukuba, Ibaraki 305-8568, Japan

The University of Tokyo 2 Research Center for Spectrochemistry, , Bunkyo-ku, Tokyo, 113-0033, Japan

National Renewable Energy Laboratory 3 The Chemical and Materials Science Center, , Golden, Colorado, 80401, USA

Lawrence Berkeley National Laboratory 4 Advanced Light Source, , Berkeley, California, 94720, USA

University of California 5 Department of Chemistry and Biochemistry, , Santa Cruz, California, 95064, USA.

The University of Tokyo 6 Department of Complexity Science and Engineering, , Kashiwa, Chiba, 277-8561, Japan

Jilin University 7 College of Physics/State Key Laboratory of Superhard Materials, , Changchun, 130012, People’s Republic of China

University of Waterloo 8 Department of Physics and Astronomy, , Waterloo, Ontario, N2L 3G1, Canada

University of Saskatchewan 9 Canadian Light Source, , Saskatoon, Saskatchewan, S7N 0X4, Canada

The University of Tokyo 10 Institute for Solid State Physics, , Kashiwa, Chiba, 277-8581, Japan

References (33)

Show source-provided references
1. J. Solid State Chem. · 1997 · 133 · 58710.1006/jssc.1997.7615 ↗
2. J. Power Sources · 2011 · 196 · 682810.1016/j.jpowsour.2010.09.105 ↗
3. 2008
4. J. Electron Spectrosc. Relat. Phenom. · 1994 · 67 · 52910.1016/0368-2048(93)02041-J ↗
5. Phys. Rev. B · 1993 · 47 · 1410310.1103/PhysRevB.47.14103 ↗
6. Appl. Phys. Lett. · 2012 · 100 · 19390610.1063/1.4711801 ↗
7. Energy Environ. Sic. · 2012 · 5 · 700710.1039/c2ee03445j ↗
8. Phys. Rev. B · 2011 · 83 · 08110610.1103/PhysRevB.83.081106 ↗
9. Sci. Rep. · 2011 · 1 · 18210.1038/srep00182 ↗
10. Phys. Rev. Lett. · 2013 · 111 · 08300210.1103/PhysRevLett.111.083002 ↗
11. J. Phys. Chem. Lett. · 2012 · 3 · 344810.1021/jz301486u ↗
12. Environ. Sci. Technol. · 2012 · 46 · 316310.1021/es203816x ↗
13. J. Power Sources · 2014 · 248 · 99410.1016/j.jpowsour.2013.10.030 ↗
14. Appl. Phys. Lett. · 2010 · 97 · 02210610.1063/1.3463468 ↗
15. Nature Chem. · 2010 · 2 · 85310.1038/nchem.768 ↗
16. Nature Chem. · 2012 · 4 · 76510.1038/nchem.1430 ↗
17. Nature Chem. · 2012 · 4 · 76610.1038/nchem.1431 ↗
18. Nature Chem. · 2012 · 4 · 76710.1038/nchem.1449 ↗
19. J. Phys. Condens. Matter · 2012 · 24 · 45220110.1088/0953-8984/24/45/452201 ↗
20. J. Electrochem. Soc. · 1997 · 144 · 118810.1149/1.1837571 ↗
21. J. Electrochem. Soc. · 1997 · 144 · 20510.1149/1.1837386 ↗
22. J. Appl. Phys. · 2007 · 102 · 11390610.1063/1.2821359 ↗
23. Adv. Energy Mater. · 2012 · 2 · 102810.1002/aenm.201200085 ↗
24. CrystEngComm · 2013 · 15 · 259210.1039/c3ce26972h ↗
25. J. Phys. Soc. Jpn. · 2010 · 79 · 11472210.1143/JPSJ.79.114722 ↗
26. J. Electron Spectrosc. Relat. Phenom. · 2012 · 185 · 16710.1016/j.elspec.2012.06.013 ↗
27. J. Phys. Chem. C · 2012 · 116 · 2489610.1021/jp310328q ↗
28. Phys. Chem. Chem. Phys. · 2014 · 16 · 703110.1039/c3cp55471f ↗
29. J. Am. Chem. Soc. · 2012 · 134 · 1370810.1021/ja303225e ↗
30. J. Phys. Chem. C · 2011 · 115 · 2551910.1021/jp208069m ↗
31. Rev. Sci. Instrum. · 2006 · 77 · 11310810.1063/1.2372731 ↗
32. Rev. Sci. Instrum. · 2012 · 83 · 01311610.1063/1.3680559 ↗
33. Phys. Rev. B · 2005 · 71 · 020406(R)10.1103/PhysRevB.71.020406 ↗