journal article·2015-05-12

Ferroelectric and dielectric properties of Nd 2−x Ce x Ti 2 O 7 ceramics

Z. P. Gao, B. Shi, H. Ye, H. X. Yan, M. J. Reece

Advances in Applied Ceramics· Volume 114· Issue 4
Publisher page

Abstract

The solid solution system Nd2−xCexTi2O7 has been investigated. The solubility limit of Ce in Nd2−xCexTi2O7 was found to be 0·5–0·75 according to X-ray diffraction and X-ray photoelectron spectroscopy results. Ce substitution increases the b and c axes and the volume of the unit cell due to its larger ionic radius. Nd2−xCexTi2O7 (x = 0·05, 0·25, 0·5, 0·75) textured ceramics were fabricated using spark plasma sintering. The ferroelectric and dielectric properties of the ceramics were studied. Ce substitution decreases the Curie point Tc of Nd2−xCexTi2O7 compounds. The results suggest that the Tc of Ce2Ti2O7 is <1445°C.
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OpenAlex topics: Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis · Nuclear materials and radiation effects

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