Circularly Polarized Long‐Persistent and Photostimulated Luminescence Enabled through Förster Resonance Energy Transfer and Upconversion Strategies

ABSTRACT Circularly polarized luminescence (CPL) has attracted significant attention for applications in displays, data encryption, anti‐counterfeiting, and bioimaging. However, extending the emission lifetime beyond the second timescale remains a challenge. Here, we report circularly polarized long‐persistent luminescence (CP‐LPL) and the first evidence of circularly polarized photostimulated luminescence (CP‐PSL) in purely organic systems. Using the chiral emitter R/S ‐OBN‐Cz, we establish two complementary design strategies: (i) a three‐component Förster resonance energy transfer (FRET) system, where the energy of long‐lived charge‐separated states between the donor and the acceptor is transferred to the chiral dopant, and (ii) a two‐component upconversion system, where the locally excited state of chiral emitter is restored upon charge recombination. Both approaches result in CP‐LPL with mirror‐image CPL signals. Moreover, in the three‐component FRET system, trapped charges in the chiral dopant can be released upon near‐infrared stimulation, regenerating circularly polarized emission. This work establishes new proof of concept in chiroptical materials research, paving the way toward the practical applications in encrypted optical storage and advanced photonic devices.