journal article·2017-08Open access

Coupling Reactions: A Conjugated Microporous Polymer for Palladium‐Free, Visible Light‐Promoted Photocatalytic Stille‐Type Coupling Reactions (Adv. Sci. 8/2017)

Saman Ghasimi, Simon A. Bretschneider, Wei Huang, Katharina Landfester, Kai A. I. Zhang

Advanced Science· Volume 4· Issue 8

Abstract

Bye bye palladium. Kai A. I. Zhang and co-workers develope a palladium-free and photocatalytic Stille-type coupling reaction of aryl iodides and aryl stannanes by a conjugated microporous polymer-based photocatalyst under visible light irradiation at room temperature in article number 1700101. Via the aryl radical-mediated reaction pathway, the light-promoted coupling reaction using a pure organic photocatalyst offers a simple, sustainable, and more economic aromatic CC bond formation mechanism.
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Research context

OpenAlex topics: Chemical Synthesis and Reactions · Covalent Organic Framework Applications · Sulfur-Based Synthesis Techniques

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Affiliations

Max Planck Institute for Polymer Research Ackermannweg 10 Mainz 55128 Germany

References

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