[GeRu6(CO)18HI]: A Germanium‐Centered Ruthenium Carbonyl Cluster with Aromatic Ring Current
Source abstract
Abstract
Abstract The carbonyl cluster compound [GeRu6(CO)18HI] is unique in regard to its structure and bonding with a GeRu6 cluster core, a planar GeRu4HI unit, extensive multi‐center bonding, and an aromatic ring current similar to benzene (9‐10 nA T−1). The open‐shell cluster core is a Ge‐centered five‐membered Ru4(Ru2) ring with CO ligands and an additional H and I atom, each bridging two Ru atoms on opposite sides of the cluster core. The compound is prepared at 130 °C in a weakly‐coordinating ionic liquid.
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Research context
OpenAlex topics: Synthesis and characterization of novel inorganic/organometallic compounds · Organometallic Complex Synthesis and Catalysis · Coordination Chemistry and Organometallics
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Affiliations
Institute for Inorganic Chemistry Karlsruhe Institute of Technology (KIT) Engesserstraße 15 D‐76131 Karlsruhe Germany
Fachbereich Chemie Philipps‐Universität Marburg Hans‐Meerwein‐Straße 4 D‐35043 Marburg Germany
Institute of Physical Chemistry Karlsruhe Institute of Technology (KIT) Fritz‐Haber‐Weg 2 D‐76131 Karlsruhe Germany
Funding
Deutsche Forschungsgemeinschaft
References (28)
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