journal article·2021-12Open access

A 4D Printable Shape Memory Vitrimer with Repairability and Recyclability through Network Architecture Tailoring from Commercial Poly(ε‐caprolactone) (Adv. Sci. 24/2021)

Jungho Joe, Jeehae Shin, Yong‐Seok Choi, Jae Hyuk Hwang, Sang Hwa Kim, Jiseok Han, Bumsoo Park, Woohwa Lee, Sungmin Park, Yong Seok Kim, Dong‐Gyun Kim

Advanced Science· Volume 8· Issue 24

Abstract

4D Printable Mutifunctional Vitrimers In article number 2103682, Sungmin Park, Yong Seok Kim, Dong‐Gyun Kim, and co‐workers develop a 4D printable vitrimer that is translated from a commercial poly‐ε‐caprolactone (PCL) resin. The developed material exhibits combined characteristics of vitrimers and semi‐crystalline PCL, allowing for self‐repairing, welding, recycling, as well as thermadapt shape memory effects. Furthermore, active dynamic network rearrangement capabilities of vitrimers permits applying various types of fused‐deposition‐modeling‐based printing methods. [Image: see text]
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Research context

OpenAlex topics: Polymer composites and self-healing · Advanced Polymer Synthesis and Characterization · Photopolymerization techniques and applications

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