Single Molecule Magnets: Single Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy‐Oxide Clusterfullerene Dy2O@C82 (Adv. Sci. 20/2019)
Source abstract
Abstract
In article number 1901352, Fupin Liu, Stanislav M. Avdoshenko, Alexey A. Popov, Ning Chen, and co-workers synthesize a new class of single-molecule magnets (SMMs) based on fullerenes encapsulating Dy2O species. The endohedral Dy–(μ2-O)–Dy units have a bent shape with unusually short Dy–O bonds. All three isomers of Dy2O@C82 show SMM behavior with broad magnetic hysteresis. Magnetic moments of Dy ions are aligned along the Dy–O bonds and are strongly antiferromagnetically coupled.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Magnetism in coordination complexes · Lanthanide and Transition Metal Complexes · Polyoxometalates: Synthesis and Applications
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Affiliations
College of Chemistry Chemical Engineering and Materials Science Soochow University Suzhou Jiangsu 215123 P. R. China
Leibniz Institute for Solid State and Materials Research (IFW Dresden) Helmholtzstrasse 20 01069 Dresden Germany
References
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