journal article·2017-10Open access

Photothermal Catalysis: Photothermal Catalyst Engineering: Hydrogenation of Gaseous CO2 with High Activity and Tailored Selectivity (Adv. Sci. 10/2017)

Jia Jia, Hong Wang, Zhuole Lu, Paul G. O'Brien, Mireille Ghoussoub, Paul Duchesne, Ziqi Zheng, Peicheng Li, Qiao Qiao, Lu Wang, Alan Gu, Feysal M. Ali, Yuchan Dong, Qiang Wang, Kulbir Kaur Ghuman, Thomas Wood, Chenxi Qian, Yue Shao, Chenyue Qiu, Miaomiao Ye, Yimei Zhu, Zheng‐Hong Lu, Peng Zhang, Amr S. Helmy, Chandra Veer Singh, Nazir P. Kherani, Doug D. Perovic, Geoffrey A. Ozin

Advanced Science· Volume 4· Issue 10

Abstract

The size dependence of the photothermal effect of palladium nanocrystals enables the selectivity of the solar powered heterogeneous catalytic hydrogenation of carbon dioxide to be finely tailored towards producing either carbon monoxide through the reverse water gas shift reaction, CO2 + H2 → CO + H2O, favored for small nanocrystals or to methane, via the Sabatier methanation reaction, CO2 + 4H2 → CH4 + 2H2O, preferred for larger nanocrystals. This is described by Geoffrey A. Ozin and co-workers in article number 1700252.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Catalytic Processes in Materials Science · CO2 Reduction Techniques and Catalysts

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Affiliations

Department of Materials Science and Engineering University of Toronto 184 College Street Toronto Ontario M5S 3E4 Canada

Materials Chemistry and Nanochemistry Research Group Solar Fuels Cluster Department of Chemistry University of Toronto 80 St. George Street Toronto Ontario M5S 3H6 Canada

Department of Chemical Engineering and Applied Chemistry University of Toronto 200 College Street Toronto Ontario M5S 3E5 Canada

Department of Mechanical Engineering Lassonde School of Engineering York University Toronto M3J 1P3 Canada

Department of Chemistry Dalhousie University 6274 Coburg Road, P.O. Box 15000 Halifax Nova Scotia B3H 4R2 Canada

Condensed Matter Physics and Materials Science Department Brookhaven National Laboratory Upton NY 11973 USA

Department of Physics Temple University Philadelphia PA 19122 USA

State Key Laboratory of Coal Conversion Institute of Coal Chemistry The Chinese Academy of Sciences Taiyuan 030001 P. R. China

Zhejiang Key Laboratory of Drinking Water Safety and Distribution Technology Zhejiang University Hangzhou 310058 P. R. China

Department of Electrical and Computing Engineering University of Toronto 10 King's College Road Toronto Ontario M5S 3G4 Canada

References

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