Electric Field‐Driven Conformational Changes in Molecular Memristor and Synaptic Behavior

Abstract This paper demonstrates the use of molecular artificial synapses in neuromorphic computing systems designed for low energy consumption. A molecular junction, based on self‐assembled monolayers (SAMs) of alkanethiolates terminated with 2 , 2 ′‐bipyridine complexed with cobalt chloride, exhibits synaptic behaviors with an energy consumption of 8.0 pJ µm ⁻² . Conductance can be modulated simply by applying pulses in the incoherent charge transport (CT) regime. Charge injection in this regime allows molecules to overcome the low energy barrier for C─C bond rotations, resulting in conformational changes in the SAMs. The reversible potentiation/depression process of conductance achieves 90% accuracy in recognizing patterns from the Modified National Institute of Standards and Technology (MNIST) handwritten digit database. The molecular junction further exhibits both rectifying and conductance hysteresis behaviors, showing potential for use in selector‐free synaptic arrays that efficiently suppress sneak currents.