Highly Crowded Twisted Thienylene‐Phenylene Structures: Evidence for Through‐Space Orbital Coupling in a [4]Catenated Topology
Source abstract
Abstract
Abstract Sterically highly crowded and twisted thienylene‐phenylenes are synthesized and structurally characterized. Single‐crystal X‐ray structure analyses and theoretical studies give evidence of through‐space delocalization of π‐electrons of peripheral (hetero)aromatic rings in toroidal and catenated topology.
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Research context
OpenAlex topics: Synthesis and Properties of Aromatic Compounds · Surface Chemistry and Catalysis · Fullerene Chemistry and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institute of Organic Chemistry II and Advanced Materials University of Ulm Albert‐Einstein‐Allee 11 Ulm 89081 Germany
PPG Industries Lackfabrik GmbH Erlenbrunnenstraße 22 Bodelshausen 72411 Germany
Otto Diels‐Institute of Organic Chemistry Christian‐Albrechts University Kiel Otto‐Hahn‐Platz 4 Kiel 24098 Germany
Funding
Universität Ulm
References (32)
Show source-provided references
1. 10.1021/cr97007310.1021/cr970073 ↗
2. 10.1002/anie.20035285510.1002/anie.200352855 ↗
3. 10.1039/C8SC03780A10.1039/C8SC03780A ↗
4. 10.1016/j.tet.2006.03.07110.1016/j.tet.2006.03.071 ↗
5. 10.1002/ejoc.20190163710.1002/ejoc.201901637 ↗
6. 10.1021/acs.inorgchem.7b0252310.1021/acs.inorgchem.7b02523 ↗
7. 10.1021/ja00010a07210.1021/ja00010a072 ↗
8. 10.1039/c1sc00358e10.1039/c1sc00358e ↗
9. 10.1246/cl.14094410.1246/cl.140944 ↗
10. Ogliaruso M. A. · Chem. Rev. · 1965 · 65 · 293
11. 10.1021/ed071pA14210.1021/ed071pA142 ↗
12. Leitner T. D. · 2018
13. 10.1038/nchem.251610.1038/nchem.2516 ↗
14. 10.1002/jlac.1948560010410.1002/jlac.19485600104 ↗
15. 10.1002/jlac.1948560010210.1002/jlac.19485600102 ↗
16. 10.1021/cr990281x10.1021/cr990281x ↗
17. 10.1016/j.tet.2008.03.07910.1016/j.tet.2008.03.079 ↗
18. 10.1002/adsc.20060032510.1002/adsc.200600325 ↗
19. 10.1021/cr00089a00610.1021/cr00089a006 ↗
20. Schore N. E. · 1991
21. 10.1021/ic50065a00710.1021/ic50065a007 ↗
22. 10.1002/ange.1984096080410.1002/ange.19840960804 ↗
23. 10.1002/anie.19840539310.1002/anie.198405393 ↗
24. 10.1021/ja000832x10.1021/ja000832x ↗
25. Cheung E. Y. · Acta Crystallogr. · 2014 · 70 · 547
26. 10.1002/jhet.557034053010.1002/jhet.5570340530 ↗
27. 10.1021/jp003442610.1021/jp0034426 ↗
28. 10.1021/cr030090110.1021/cr0300901 ↗
29. Frisch M. J. · 2016
30. 10.1246/cl.1994.133310.1246/cl.1994.1333 ↗
31. 10.1016/0009-2614(92)85733-Q10.1016/0009-2614(92)85733-Q ↗
32. 10.1063/1.46491310.1063/1.464913 ↗