Laser‐Induced Graphene from Commercial Inks and Dyes

Abstract Laser‐induced graphene (LIG) has been so far obtained from polymer precursors and proposed for numerous applications, including various types of sensors and energy storage solutions. This study examines a radically different class of new precursors for LIG, distinct from polymers: inks and dyes. The identification of specific organic dyes present in commercial markers demonstrates that the aromatic structure, in conjunction with high thermal stability (residual weight > 20% at 800°C), are key factors for laser‐induced pyrolysis. Eosin Y is identified as an excellent LIG precursor, comparable with well‐known polyimide. The unique properties of dyes allow for dispersion in various media, such as acrylic binder. A dye concentration of 0.75 mol L ⁻¹ in acrylic binder results in a conductivity of 34 ± 20 S cm ⁻¹ for LIG. The composition and microstructure of LIG from dyes are thoroughly characterized, revealing peculiar features. A versatile “Paint & Scribe” methodology is introduced, enabling to integrate LIG tracks onto any wettable surface, and in particular onto printed and flexible electronics. A process for obtaining freestanding and transferrable LIG is demonstrated by dissolving acrylic paint in acetone and floating LIG in water. This advancement offers novel avenues for diverse applications that necessitate a transfer process of LIG.