Controllable Friction on Graphene via Adjustable Interfacial Contact Quality

Abstract Despite the numerous unique properties revealed through tribology research on graphene, the development of applications that utilize its rich tribological properties remains a long‐sought goal. In this article, a novel approach for reversible patterning of graphene's frictional properties using out‐of‐plane mechanical tapping is presented. The friction force between the atomic force microscopy (AFM) tip and the graphene film is increased by up to a factor of two, which can be attributed to variations in the interfacial binding strength between the graphene and substrate through the tapping process. The reversible and repeatable frictional properties of graphene make it a promising material for information storage applications with a high storage capacity of ≈1600 GB inch⁻², allowing for direct writing and erasing of information, akin to a blackboard. These findings highlight the potential for friction tuning in lamellar materials and emphasize the significance of understanding nanoscale friction on graphene surfaces.