3D Cellular Solar Crystallizer for Stable and Ultra‐Efficient High‐Salinity Wastewater Treatment

Abstract Recent developed interfacial solar brine crystallizers, which employ solar‐driven water evaporation for salts crystallization from the near‐saturation brine to achieve zero liquid discharge (ZLD) brine treatment, are promising due to their excellent energy efficiency and sustainability. However, most existing interfacial solar crystallizers are only tested using NaCl solution and failed to maintain high evaporation capability when treating real seawater due to the scaling problem caused by the crystallization of high‐valent cations. Herein, an artificial tree solar crystallizer (ATSC) with a multi‐branched and interconnected open‐cell cellular structure that significantly increased evaporation surface is rationally designed, achieving an ultra‐high evaporation rate (2.30 kg m⁻² h⁻¹ during 2 h exposure) and high energy efficiency (128%) in concentrated real seawater. The unit cell design of ATSC promoted salt crystallization on the outer frame rather than the inner voids, ensuring that salt crystallization does not affect the continuous transport of brine through the pores inside the unit cell, thus ATSC can maintain a stable evaporation rate of 1.94 kg m⁻² h⁻¹ on average in concentrated seawater for 80 h continuous exposure. The design concept of ATSC represents a major step forward toward ZLD treatment of high‐salinity brine in many industrial processes is believed.