journal article·2021-05

Emergent Midgap Excitons in Large‐Size Freestanding 2D Strongly Correlated Perovskite Oxide Films (Advanced Optical Materials 10/2021)

Yuguo Zhang, Haijiao Harsan Ma, Xin Gan, Yupeng Hui, Yueying Zhang, Jie Su, Ming Yang, Zhaosheng Hu, Juanxiu Xiao, Xiaoli Lu, Jincheng Zhang, Yue Hao

Advanced Optical Materials· Volume 9· Issue 10
Publisher page

Abstract

Achievement of large-size (1 × 1 cm2) freestanding strongly correlated perovskite SrTiO3 films is demonstrated by Haijiao Harsan Ma and co-workers in article number 2100025. Two emergent photoluminescence peaks are observed at ≈2.4 eV (green) and ≈1.8 eV (red) which are absent in its 3D bulk form or as-grown films unexfoliated. The green peak originates from self-trapped excitons localized within TiO6 octahedra and the red peak is related to Ti vacancies. The observation is promising for potential application of 2D perovskite oxide films in high-performance optoelectronics.
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Research context

OpenAlex topics: Perovskite Materials and Applications

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Affiliations

Low Dimensional Quantum Physics and Device Group School of Microelectronics Xidian University 2 South Taibai Road Xi'an 710071 China

State Key Discipline Laboratory of Wide Band Gap Semiconductor Technology School of Microelectronics Xidian University 2 South Taibai Road Xi'an 710071 China

Department of Applied Physics The Hong Kong Polytechnic University Hung Hom Hong Kong China

State Key Laboratory of Marine Resource Utilization in South China Sea Hainan University No. 58, Renmin Avenue Haikou Hainan 570228 China

References

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