journal article·2024-04Open access

Striking Change in Radiative Lifetime and Asymmetry Ratio with Temperature for the Double Perovskite Cs2NaEuCl6

Daiwen Xiao, Hei‐Yui Kai, Guohua Jia, Ka‐Leung Wong, Peter A. Tanner

Advanced Optical Materials· Volume 12· Issue 10

Abstract

Abstract The measurement of quantum yield (QY) is an important process for a phosphor. This is often accomplished by the comparison of the low‐temperature lifetime with the room temperature (RT) lifetime. It is shown that this procedure provides a considerable underestimation of QY in certain cases. Additionally, the use of the europium ion as an indicator of changes in site symmetry with temperature has severe limitations. This work reveals that a decrease in measured lifetime with increasing temperature of a system cannot always be associated with a descent in site symmetry and may be due to increasing radiative rate.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Perovskite Materials and Applications · Lanthanide and Transition Metal Complexes · Luminescence Properties of Advanced Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry Hong Kong Baptist University Waterloo Road Kowloon Tong Hong Kong SAR P. R. China

School of Molecular and Life Sciences Curtin University Kent Street Bentley WA 6102 Australia

Department of Applied Biology and Chemical Technology The Hong Kong Polytechnic University Hung Hom Kowloon Hong Kong SAR P. R. China

Funding

Australian Research Council

References (43)

Show source-provided references
1. 10.1002/advs.20200411810.1002/advs.202004118 ↗
2. Li X. · Adv. Sci. · 2023 · 10
3. 10.1039/D2QI02053J10.1039/D2QI02053J ↗
4. 10.1038/s41377-023-01117-210.1038/s41377-023-01117-2 ↗
5. 10.1016/S0009-2614(02)00106-910.1016/S0009-2614(02)00106-9 ↗
6. 10.1063/1.138703810.1063/1.1387038 ↗
7. 10.1002/anie.20221266810.1002/anie.202212668 ↗
8. 10.1007/s40820-019-0244-610.1007/s40820-019-0244-6 ↗
9. 10.1039/D2MA00071G10.1039/D2MA00071G ↗
10. 10.1002/adom.20230027710.1002/adom.202300277 ↗
11. 10.1021/ja036659x10.1021/ja036659x ↗
12. 10.1063/1.45434210.1063/1.454342 ↗
13. 10.1021/ic50157a00210.1021/ic50157a002 ↗
14. 10.1080/0026897770010178110.1080/00268977700101781 ↗
15. 10.1039/f2987830136710.1039/f29878301367 ↗
16. 10.1088/0953-8984/6/8/01710.1088/0953-8984/6/8/017 ↗
17. 10.1016/0301-0104(84)85212-X10.1016/0301-0104(84)85212-X ↗
18. 10.1080/0026897860010118110.1080/00268978600101181 ↗
19. 10.1039/D1TC05587A10.1039/D1TC05587A ↗
20. 10.1080/0026897850010324110.1080/00268978500103241 ↗
21. 10.1021/jacs.7b0855910.1021/jacs.7b08559 ↗
22. 10.1016/j.inoche.2018.09.04110.1016/j.inoche.2018.09.041 ↗
23. 10.1021/jp953702x10.1021/jp953702x ↗
24. 10.1021/j100053a03010.1021/j100053a030 ↗
25. 10.1021/jp077001z10.1021/jp077001z ↗
26. 10.1039/b107770h10.1039/b107770h ↗
27. 10.1021/acs.jpclett.3c0139110.1021/acs.jpclett.3c01391 ↗
28. 10.1021/acsomega.8b0112710.1021/acsomega.8b01127 ↗
29. 10.1021/jacs.6b0098410.1021/jacs.6b00984 ↗
30. 10.1021/ja511652410.1021/ja5116524 ↗
31. 10.1021/ja074119k10.1021/ja074119k ↗
32. 10.1021/ja407924m10.1021/ja407924m ↗
33. 10.1016/0009-2614(83)80342-X10.1016/0009-2614(83)80342-X ↗
34. 10.1063/1.44406810.1063/1.444068 ↗
35. 10.1080/0026897810010228110.1080/00268978100102281 ↗
36. 10.1016/0925-8388(94)90077-910.1016/0925-8388(94)90077-9 ↗
37. 10.1016/S0010-8545(00)80451-810.1016/S0010-8545(00)80451-8 ↗
38. 10.1088/0953-8984/3/36/01110.1088/0953-8984/3/36/011 ↗
39. Duckett M. R. · SPIE · 1997 · 3176 · 108
40. 10.1016/j.ccr.2015.02.01510.1016/j.ccr.2015.02.015 ↗
41. Chen X. · Appl. Phys. Lett. · 2017 · 110 · 5
42. 10.1021/acs.chemmater.2c0260910.1021/acs.chemmater.2c02609 ↗
43. 10.1021/acs.inorgchem.1c0318810.1021/acs.inorgchem.1c03188 ↗