journal article·2021-09Open access

High Optical Performance of Cyan‐Emissive CsPbBr3 Perovskite Quantum Dots Embedded in Molecular Organogels

Marta Vallés‐Pelarda, Andrés F. Gualdrón‐Reyes, Carles Felip‐León, César A. Angulo‐Pachón, Said Agouram, Vicente Muñoz‐Sanjosé, Juan F. Miravet, Francisco Galindo, Iván Mora‐Seró

Advanced Optical Materials· Volume 9· Issue 18

Abstract

Abstract Perovskite quantum dots (PQDs) have fascinating optoelectronic properties, such as high photoluminescence quantum yield (PLQY) for a broad range of materials, and the possibility to obtain different bandgaps with the same material or halide combinations. Nevertheless, blue‐emissive materials generally present limited PLQY or color instability. Here, two molecular organogels, based on a derivative of an amino acid and succinic acid, are used to embed CsPbBr3 quantum dots, obtaining green and blue emission. Transmission electron microscopy (TEM) and selected area electron diffraction (SAED) measurements are performed to confirm that there are no significant changes in the average size of the QDs and the crystal structure. A high near‐unity PLQY is achieved for the blue emission. This contribution opens the door to a postsynthetic treatment for synthesizing blue‐emissive PQDs with high optical performance, which can be attractive for optoelectronic applications.
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Research context

OpenAlex topics: Perovskite Materials and Applications · Luminescence and Fluorescent Materials · 2D Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Advanced Materials (INAM) University Jaume I Av. de Vicent Sos Baynat Castelló de la Plana s/n 12006 Spain

Department of Inorganic and Organic Chemistry University Jaume I Av. de Vicent Sos Baynat Castelló de la Plana s/n 12006 Spain

Department of Applied Physics and Electromagnetism University of Valencia Valencia 46100 Spain

Materials for Renewable Energy (MAER) Unitat Mixta d'Investigació UV‐UJI Valencia 46010 Spain

Funding

European Research Council

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