Recent Advances in the A‐Site Cation Engineering of Lead Halide Perovskites
Source abstract
Abstract
Abstract Lead halide perovskite (LHP) have gained considerable research attention for their numerous photoelectric applications attributed to their ease of processability and distinctive photoelectric properties. A‐site cation engineering provides an effective solution to optimize the bandgap further, enhance stability, and improve the photoelectric properties of LHP materials. In this review, an in‐depth examination of the progress achieved in the field of A‐site cation engineering on the structure, properties, synthesis methods, and photoelectric applications of LHP is presented. It is discussed how A‐site cations can change the crystal structure and improve the crystal quality, and how the A‐site cation regulates the bandgap, enhances stability, and promotes effective charge transport. Further, synthesis strategy is presented to regulate the A‐site cation. Subsequently, the applications of A‐site cation‐regulated LHP materials in solar cells, light‐emitting diodes, photodetectors, and lasers are introduced. Finally, challenges that must be overcome to further improve the properties and stability of LHP materials via A‐site cation engineering are highlighted.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Perovskite Materials and Applications · Advancements in Solid Oxide Fuel Cells · Electronic and Structural Properties of Oxides
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Physics and Mechanical and Electrical Engineering Hubei University of Education Wuhan 430205 P. R. China
State Key Laboratory of Infrared Physics Shanghai Institute of Technical Physics Chinese Academy of Sciences Shanghai 200083 China
Material Science and Engineering Program and Texas Center for Superconductivity at University of Houston (TcSUH) University of Houston TX 77204 USA
School of Electronic Electrical and Communication Engineering University of Chinese Academy of Sciences Beijing 100049 P. R. China
Hangzhou Institute for Advanced Study University of Chinese Academy of Sciences Hangzhou 310024 P. R. China
Engineering Research Center of Nano‐Geomaterials of Ministry of Education Faculty of Materials Science and Chemistry China University of Geosciences Wuhan 430074 P. R. China
Funding
National Natural Science Foundation of China · Natural Science Foundation of Hubei Province · Hubei University of Education · Basic and Applied Basic Research Foundation of Guangdong Province · Shenzhen Science and Technology Innovation Program
References (100+)
Show source-provided references
1. 10.1039/D2CS00218C10.1039/D2CS00218C ↗
2. 10.1002/adfm.20230594110.1002/adfm.202305941 ↗
3. 10.1038/s41563-020-00826-y10.1038/s41563-020-00826-y ↗
4. 10.1039/D2EE01634F10.1039/D2EE01634F ↗
5. 10.1002/adfm.20210944210.1002/adfm.202109442 ↗
6. 10.1002/adom.20210266110.1002/adom.202102661 ↗
7. 10.1126/science.aat505510.1126/science.aat5055 ↗
8. 10.1038/s41928-019-0355-610.1038/s41928-019-0355-6 ↗
9. 10.1021/acssuschemeng.9b0305810.1021/acssuschemeng.9b03058 ↗
10. Rolston N. · Adv. Energy Mater. · 2018 · 8
11. Lee J.‐W. · Nano Lett. · 2017 · 17
12. 10.1021/acs.nanolett.5b0406010.1021/acs.nanolett.5b04060 ↗
13. 10.1038/nenergy.2016.8110.1038/nenergy.2016.81 ↗
14. 10.1038/ncomms640410.1038/ncomms6404 ↗
15. 10.1039/C4CC05960C10.1039/C4CC05960C ↗
16. Tong G. · Adv. Funct. Mater. · 2020 · 30
17. 10.1002/adom.20190098810.1002/adom.201900988 ↗
18. Li F. · Nat. Commun. · 2015 · 6
19. 10.1038/s41928-018-0101-510.1038/s41928-018-0101-5 ↗
20. 10.1002/smll.20180276410.1002/smll.201802764 ↗
21. 10.1186/s43593-023-00047-110.1186/s43593-023-00047-1 ↗
22. 10.1126/science.aad181810.1126/science.aad1818 ↗
23. 10.1038/s41566-019-0559-310.1038/s41566-019-0559-3 ↗
24. 10.1038/nphoton.2016.18510.1038/nphoton.2016.185 ↗
25. 10.1038/nnano.2016.11010.1038/nnano.2016.110 ↗
26. 10.1038/nnano.2014.14910.1038/nnano.2014.149 ↗
27. 10.1016/j.nanoen.2017.10.01210.1016/j.nanoen.2017.10.012 ↗
28. 10.1038/srep3354610.1038/srep33546 ↗
29. 10.1002/adma.20160136910.1002/adma.201601369 ↗
30. 10.1002/adma.20221061110.1002/adma.202210611 ↗
31. 10.1021/acs.chemrev.9b0059210.1021/acs.chemrev.9b00592 ↗
32. 10.1038/ncomms905610.1038/ncomms9056 ↗
33. 10.1021/nn504856g10.1021/nn504856g ↗
34. 10.1021/jacs.5b1266210.1021/jacs.5b12662 ↗
35. 10.1021/acsphotonics.7b0071310.1021/acsphotonics.7b00713 ↗
36. 10.1021/acs.nanolett.8b0099010.1021/acs.nanolett.8b00990 ↗
37. 10.1038/s41566-017-0047-610.1038/s41566-017-0047-6 ↗
38. 10.1002/smtd.20170016310.1002/smtd.201700163 ↗
39. 10.1002/adma.20170723510.1002/adma.201707235 ↗
40. 10.1002/adma.20150256710.1002/adma.201502567 ↗
41. 10.1021/nl504877910.1021/nl5048779 ↗
42. 10.1002/aenm.20160130710.1002/aenm.201601307 ↗
43. 10.1021/jacs.9b0097210.1021/jacs.9b00972 ↗
44. 10.1021/acsnano.8b0555510.1021/acsnano.8b05555 ↗
45. 10.1021/acsami.8b0004810.1021/acsami.8b00048 ↗
46. 10.1039/c3ee43822h10.1039/c3ee43822h ↗
47. 10.1021/nl400349b10.1021/nl400349b ↗
48. 10.1021/acs.jpcc.6b0691410.1021/acs.jpcc.6b06914 ↗
49. 10.1039/C9NR02733E10.1039/C9NR02733E ↗
50. 10.1021/acsnano.8b0112210.1021/acsnano.8b01122 ↗
51. 10.1126/science.aag270010.1126/science.aag2700 ↗
52. 10.1021/jz501237m10.1021/jz501237m ↗
53. 10.1021/jacs.6b0890010.1021/jacs.6b08900 ↗
54. 10.1039/C8CS00212F10.1039/C8CS00212F ↗
55. 10.1016/j.orgel.2019.10554610.1016/j.orgel.2019.105546 ↗
56. Lee J. · Science · 2022 · 835
57. 10.1002/adom.20220042310.1002/adom.202200423 ↗
58. 10.1038/ncomms714210.1038/ncomms7142 ↗
59. 10.1126/science.abb898510.1126/science.abb8985 ↗
60. 10.1039/C7RA12521F10.1039/C7RA12521F ↗
61. 10.1038/s41467-019-08326-710.1038/s41467-019-08326-7 ↗
62. Wu C. · Phys. Chem. Chem. Phys. · 2020 · 22
63. 10.1007/s11426-018-9325-710.1007/s11426-018-9325-7 ↗
64. 10.1021/acsnano.5b0115410.1021/acsnano.5b01154 ↗
65. 10.1039/C5NR06890H10.1039/C5NR06890H ↗
66. 10.1021/acsenergylett.7b0122610.1021/acsenergylett.7b01226 ↗
67. 10.1002/adom.20220112710.1002/adom.202201127 ↗
68. 10.1039/C8TA03782E10.1039/C8TA03782E ↗
69. 10.1039/C8TC02976H10.1039/C8TC02976H ↗
70. 10.1007/s13204-019-01021-510.1007/s13204-019-01021-5 ↗
71. 10.1039/D1EE01184G10.1039/D1EE01184G ↗
72. 10.1021/acs.chemmater.9b0403210.1021/acs.chemmater.9b04032 ↗
73. 10.1021/acs.chemmater.9b0415710.1021/acs.chemmater.9b04157 ↗
74. 10.1063/5.002123810.1063/5.0021238 ↗
75. 10.1039/C8CS00740C10.1039/C8CS00740C ↗
76. Mosconi E. · ACS Energy Lett. · 2022 · 8 · 1748
77. 10.1016/j.mser.2018.12.00110.1016/j.mser.2018.12.001 ↗
78. 10.1364/OME.7.00436710.1364/OME.7.004367 ↗
79. 10.1002/adma.20180199610.1002/adma.201801996 ↗
80. 10.1021/acs.jpcc.9b1117210.1021/acs.jpcc.9b11172 ↗
81. 10.1039/C7CS00868F10.1039/C7CS00868F ↗
82. 10.1038/ncomms675710.1038/ncomms6757 ↗
83. 10.1021/acs.chemmater.8b0185110.1021/acs.chemmater.8b01851 ↗
84. 10.1021/acscentsci.9b0036710.1021/acscentsci.9b00367 ↗
85. 10.1021/jacs.9b1358710.1021/jacs.9b13587 ↗
86. 10.1039/C8TC04065F10.1039/C8TC04065F ↗
87. 10.1021/acsomega.9b0383810.1021/acsomega.9b03838 ↗
88. 10.1039/C7TA04008C10.1039/C7TA04008C ↗
89. 10.1039/C9CP06568G10.1039/C9CP06568G ↗
90. 10.1038/nature1413310.1038/nature14133 ↗
91. 10.1021/acs.chemmater.5b0410710.1021/acs.chemmater.5b04107 ↗
92. 10.1021/acs.jpclett.7b0311410.1021/acs.jpclett.7b03114 ↗
93. 10.1021/acsenergylett.0c0045010.1021/acsenergylett.0c00450 ↗
94. 10.1038/nature2598910.1038/nature25989 ↗
95. 10.1002/anie.20191128110.1002/anie.201911281 ↗
96. 10.1002/aenm.20170305710.1002/aenm.201703057 ↗
97. Wang Z. · Nat. Energy · 2017 · 2 · 91
98. 10.1039/C5EE03874J10.1039/C5EE03874J ↗
99. 10.1021/acs.chemmater.6b0071110.1021/acs.chemmater.6b00711 ↗
100. 10.1021/acsnano.6b0153510.1021/acsnano.6b01535 ↗