journal article·2004-01

Ferroelectricity in La1-xBixCrO3Solid Solutions

J. I. L. CHEN, Z. -G. YE

Ferroelectrics· Volume 301· Issue 1
Publisher page

Abstract

New perovskite solid solutions of (1 - x)LaCrO3 - xBiCrO3 (0 ≤ x ≤ 0.35) are synthesized by solid state reactions at 1200°C. The substitution of Bi2O3 for La2O3 is found to improve the density of the ceramics. Ferroelectricity is discovered in La1 - xBixCrO3 by hysteresis loops displayed at 77 K, with the remanent polarization increasing as Bi3+ content increases. Its origin is attributed to the structural distortion induced by the stereochemically active Bi3+ ion on the A-site.
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Research context

OpenAlex topics: Multiferroics and related materials · Magnetic and transport properties of perovskites and related materials · Ferroelectric and Piezoelectric Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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