Marangoni Force Assisted Spreading and Printing of Nanometer‐Thick Polymer Films for Ubiquitous Optoelectronic Devices

Abstract Printable organic electronics are attractive owing to its high throughput and easy fabrication. Traditional coating methods (such as inkjet printing) are liquid‐solid contact‐based that deposit liquid solutions onto solid surfaces. Film quality is limited by surface energy of target surfaces and surface tension of the solvents. Furthermore, these printing methods are challenging to directly fabricate films on non‐flat or curved surfaces owing to the fluidity of liquid solution drops. In this work, a water transfer printing method that is solid‐solid contact‐based and assisted by Van der Waals force is reported. Nanometer‐thick films can be deposited on various surfaces: both high‐ and low‐surface energy, both flat and non‐flat surfaces. Water plays two roles: 1) as the transfer medium substrate and providing weak adhesion force between water and the transferred film; 2) high surface tension of water providing room to create surface tension gradient and producing Marangoni force to unfold the crumpled nanometer‐thick films. Electronic and optoelectronics on wrinkled skin and curved surfaces are demonstrated with this water transfer printing method.